N,N-dimethyl(benzyl-d7)amine

Base Information

• Chemical Name: N,N-dimethyl(benzyl-d7)amine
• CAS No.: 106988-36-7
• Molecular Formula: C₉H₁₃N
• Molecular Weight: 142.153
• Mol file: 106988-36-7.mol

Synonyms:N,N-dimethyl(benzyl-d7)amine

Chemical Property of N,N-dimethyl(benzyl-d7)amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-dimethyl(benzyl-d7)amine

There total 2 articles about N,N-dimethyl(benzyl-d7)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(N,N-dimethylaminomethyl)nitrobenzene (15184-96-0) → N,N-dimethyl(benzyl-d7)amine (106988-36-7)

Guidance literature:

With deuterated ortho-palladated N,N-dimethylbenzylamine; In chloroform-d1; at 55 ℃; for 216h; Equilibrium constant; reversible reaction;

Reference yield:

{C6D4CD2N(CH3)2PdOCOCH3}2 (106988-35-6) + 4-(N,N-dimethylaminomethyl)nitrobenzene (15184-96-0) → {Pd(OCOCH3)(C7H5NO2N(CH3)2)}2 + N,N-dimethyl(benzyl-d7)amine (106988-36-7)

Guidance literature:

In chloroform-d1; addn. of the amine in CD3COOD to the complex in CDCl3, react. at 55° for 216h (equilibrium); not isolated, (1)H-NMR;

Reference yield:

{C6H4CH2N(C2H5)2PdOCOCH3}2 (107035-13-2) + N,N-dimethyl(benzyl-d7)amine (106988-36-7) → {C6D4CD2N(CH3)2PdOCOCH3}2 (106988-35-6) + N,N-diethylbenzylamine (772-54-3)

Guidance literature:

In chloroform-d1; mixing solns. of the Pd complex in CDCl3 with N,N-dimethylbenzylamine-d7 in CD3COOD and hexamethyldisiloxane, direct filtration into a NMR tube, thermostating in the dark (55°C, 216 h), intermediate filtration from Pd metal traces; not isolated; monitoring by 1H-NMR; detn. of the equilibrium constant;

upstream raw materials:

4-(N,N-dimethylaminomethyl)nitrobenzene

{C₆D₄CD₂N(CH₃)2PdOCOCH₃}2

Downstream raw materials:

N,N'-dimethylbenzylamine

N,N-diethylbenzylamine

{C₆D₄CD₂N(CH₃)2PdOCOCH₃}2

4-methyl-N,N-dimethylbenzylamine

Refernces