2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline

Base Information

• Chemical Name: 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline
• CAS No.: 1373403-63-4
• Molecular Formula: C₄₈H₄₀N₂
• Molecular Weight: 644.859
• Mol file: 1373403-63-4.mol

Synonyms:2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline

Chemical Property of 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline

There total 1 articles about 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

2,6-diphenylmethyl-4-methylaniline (56138-96-6) + 8-oxo-2-phenyl-5,6,7,8-tetrahydroquinoline (78590-01-9) → 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline (1373403-63-4)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 3h; Reflux;

DOI:10.1016/j.jorganchem.2012.02.031

Reference yield: 89.0%

nickel(II) chloride hexahydrate + 2-phenyl-8-(2,6-dibenzhydryl-4-methylphenylimino)-5,6,7-trihydroquinoline (1373403-63-4) → 2-phenyl-8-(2,6-dibenzhydryl-4-methylarylimino)-5,6,7-trihydroquinoline-N,N' nickel(II) dichloride

Guidance literature:

In ethanol; dichloromethane; Schlenk technique, under N2; mixt. of NiCl2*6H2O (EtOH) and NC9H8(Ph)NC6H2(CH3)(CHPh2)2 (CH2Cl2) (1 equiv.) stirred for 3 h; ether added, ppt. filtered off, washed with Et2O, dried under vac. at 60°C; elem. anal.;

DOI:10.1016/j.jorganchem.2012.02.031

upstream raw materials:

2,6-diphenylmethyl-4-methylaniline

8-oxo-2-phenyl-5,6,7,8-tetrahydroquinoline