(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Base Information

Chemical Name:(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene
CAS No.:118631-01-9
Molecular Formula:C₁₈H₃₁BrOSi
Molecular Weight:371.433
Hs Code.:

Synonyms:(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Suppliers and Price of (+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

There total 4 articles about (+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 159610-36-3
(+/-)-3-<4-<(tert-Butyldimethylsilyl)oxy>-3,5-dimethylphenyl>-2-methyl-1-propanol

: 118631-01-9
(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In diethyl ether; for 4h; Yield given; Ambient temperature;
DOI:10.1021/jo00100a039

Reference yield:

: 127797-68-6
2,6-Dimethyl-4-(2-methylpropenyl)phenol

: 118631-01-9
(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 4 h / Ambient temperature

2: 1.) BH₃*THF, 2.) 30percent H₂O₂, 3 N NaOH / 1.) 0 deg C, 10 min; 2 h, 2.) 0 deg C, 15 min; 1 h

3: Ph₃P, CBr₄ / diethyl ether / 4 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; borane-THF; carbon tetrabromide; dihydrogen peroxide; triphenylphosphine; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00100a039

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 118631-01-9
(+/-)-4-(3-Bromo-2-methylpropyl)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethylbenzene

Guidance literature:: Multi-step reaction with 3 steps

1: imidazole / dimethylformamide / 4 h / Ambient temperature

2: 1.) BH₃*THF, 2.) 30percent H₂O₂, 3 N NaOH / 1.) 0 deg C, 10 min; 2 h, 2.) 0 deg C, 15 min; 1 h

3: Ph₃P, CBr₄ / diethyl ether / 4 h / Ambient temperature

With 1H-imidazole; sodium hydroxide; borane-THF; carbon tetrabromide; dihydrogen peroxide; triphenylphosphine; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00100a039