1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

Base Information

Chemical Name:1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne
CAS No.:700868-22-0
Molecular Formula:C₃₂H₃₃FeN₃O₆S₃
Molecular Weight:707.676
Hs Code.:

Synonyms:1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

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Chemical Property of 1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

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Technology Process of 1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

There total 1 articles about 1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 700868-21-9
1,11-bis(tert-butyloxycarbonyl)-1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

: 700868-22-0
1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

Guidance literature:: With CF₃CO₂H; In dichloromethane; mixt. of Fe compd., trifluoroacetic acid in CH2Cl2 was stirred at room temp. for 4.5 h; distd. (vac.); residue dissolved in EtOAc; org. layer washed (aq. Na2CO3, H2O, brine); dried (Na2SO4); filtered; solvent removed (vac.); chromd.(silica gel, hexane/EtOAc, 6/4); elem. anal.;
DOI:10.1021/om034384o

Reference yield: 75.0%

: 700868-22-0
1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

: 2219-66-1
1,4-dibromobut-2-yne

: 700868-23-1
6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

Guidance literature:: With K₂CO₃; In acetonitrile; stirred mixt. Fe complex, dibromide (1.16 equiv.) and K2CO3 in CH3CN wasrefluxed for 5.5 h; filtered; filtrate evapd.; residue chromd. (silica gel, hexane/EtOAc, 9/1 to 6/4); elem. anal.;
DOI:10.1021/om034384o

Reference yield: 53.0%

: 700868-22-0
1,11-bis[(4-methylphenyl)sulfonyl]-6-ferrocenylsulfonyl-1,6,11-triazaundeca-3,8-diyne

: 2917-96-6
1,4-bis(methanesulfonyloxy)-2-butyne

: 700868-23-1
6,11-bis[(4-methylphenyl)sulfonyl]-1-ferrocenylsulfonyl-1,6,11-triazaciclopentadeca-3,8,13-triyne

Guidance literature:: With K₂CO₃; In acetonitrile; stirred mixt. Fe complex, bismethanesulfonate (1.16 equiv.) and K2CO3 inCH3CN was refluxed for 5.5 h; filtered; filtrate evapd.; residue chromd. (silica gel, hexane/EtOAc, 9/1 to 6/4);
DOI:10.1021/om034384o