Technology Process of C41H25N3O
There total 11 articles about C41H25N3O which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; sodium t-butanolate;
tris-(dibenzylideneacetone)dipalladium(0);
In
xylene;
for 14h;
Inert atmosphere;
Reflux;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: potassium carbonate; 18-crown-6 ether; tri-tert-butyl phosphine / tris-(dibenzylideneacetone)dipalladium(0) / toluene; xylene / 18 h / Inert atmosphere; Reflux
2: N-Bromosuccinimide / N,N-dimethyl-formamide / 0 °C
3: potassium acetate / (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 6 h / 80 °C / Inert atmosphere
4: potassium phosphate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / toluene; water / 5 h / Inert atmosphere; Reflux
5: sodium t-butanolate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / xylene / 14 h / Inert atmosphere; Reflux
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; N-Bromosuccinimide; 18-crown-6 ether; tri-tert-butyl phosphine; potassium acetate; potassium carbonate; sodium t-butanolate;
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; tris-(dibenzylideneacetone)dipalladium(0);
In
1,4-dioxane; water; N,N-dimethyl-formamide; toluene; xylene;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 2,4,6-Triisopropylbenzenesulfonyl azide; lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere
2: water; tetrahydrofuran
3: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / 1,2-dimethoxyethane / 48 h / Inert atmosphere; Reflux
4: 2-Methyl-2-nitropropane; sulfuric acid / acetic acid / 45 °C
5: sodium t-butanolate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / tris-(dibenzylideneacetone)dipalladium(0) / xylene / 14 h / Inert atmosphere; Reflux
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; 2-Methyl-2-nitropropane; sulfuric acid; 2,4,6-Triisopropylbenzenesulfonyl azide; potassium carbonate; sodium t-butanolate; lithium diisopropyl amide;
tris-(dibenzylideneacetone)dipalladium(0); tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran; 1,2-dimethoxyethane; water; acetic acid; xylene;