bis(2-pyridylseleno)phenylmethane

Base Information

• Chemical Name: bis(2-pyridylseleno)phenylmethane
• CAS No.: 819850-03-8
• Molecular Formula: C₁₇H₁₄N₂Se₂
• Molecular Weight: 404.232
• Mol file: 819850-03-8.mol

Synonyms:bis(2-pyridylseleno)phenylmethane

Chemical Property of bis(2-pyridylseleno)phenylmethane

Chemical Property:

Purity/Quality:

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Technology Process of bis(2-pyridylseleno)phenylmethane

There total 1 articles about bis(2-pyridylseleno)phenylmethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

benzylidene dichloride (98-87-3) + 2,2'-dipyridyldiselenide (59957-75-4) → bis(2-pyridylseleno)phenylmethane (819850-03-8)

Guidance literature:

2,2'-dipyridyldiselenide; With sodium tetrahydroborate; In ethanol; at 20 ℃; for 0.5h;

benzylidene dichloride; In ethanol; for 24h; Heating;

DOI:10.1021/jo048505l

Reference yield:

bis(2-pyridylseleno)phenylmethane (819850-03-8) + benzophenone (119-61-9) → 1,1,2-triphenyl-2-(2-pyridylseleno)ethanol + 1,1,2-triphenyl-2-(2-pyridylseleno)ethanol

Guidance literature:

With Isopropylbenzene; 2,2'-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]; In hexane; at -78 ℃; Further Variations:; Reagents; Temperatures; Product distribution;

DOI:10.1021/jo048505l

Reference yield:

bis(2-pyridylseleno)phenylmethane (819850-03-8) + 4-tercbutyl-cyclohexanone (98-53-3) → (R)-1-[1-phenyl-1-(phenylseleno)methyl]-4-tert-butylcyclohexan-1-ol + (R)-1-[1-phenyl-1-(phenylseleno)methyl]-4-tert-butylcyclohexan-1-ol + (S)-1-[1-phenyl-1-(phenylseleno)methyl]-4-tert-butylcyclohexan-1-ol (685525-97-7) + (S)-1-[1-phenyl-1-(phenylseleno)methyl]-4-tert-butylcyclohexan-1-ol

Guidance literature:

With Isopropylbenzene; 2,2'-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]; In hexane; at -78 ℃; Further Variations:; Reagents; Product distribution;

DOI:10.1021/jo048505l

upstream raw materials:

benzylidene dichloride

2,2'-dipyridyldiselenide

Downstream raw materials:

(S)-1-[1-phenyl-1-(phenylseleno)methyl]-4-tert-butylcyclohexan-1-ol

Refernces