C₇₁H₁₁₉⁽³⁾HO₁₀Si₄

Base Information

• Chemical Name: C₇₁H₁₁₉⁽³⁾HO₁₀Si₄
• CAS No.: 870646-25-6
• Molecular Formula: C₇₁H₁₂₀O₁₀Si₄
• Molecular Weight: 1248.06
• Mol file: 870646-25-6.mol

Synonyms:C₇₁H₁₁₉⁽³⁾HO₁₀Si₄

Chemical Property of C₇₁H₁₁₉⁽³⁾HO₁₀Si₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₇₁H₁₁₉⁽³⁾HO₁₀Si₄

There total 7 articles about C₇₁H₁₁₉⁽³⁾HO₁₀Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(4-iodo-benzoyl)-benzaldehyde (870646-24-5) → C71H119(3)HO10Si4 (870646-25-6)

Guidance literature:

Multi-step reaction with 3 steps

1: 79 percent / 2-methyl-2-butene; NaH₂PO₄; NaOCl₂ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 18 h

2: tritium gas / dimethylformamide

3: 8.6 mg / 4-benzoylbenzoic acid; EDCI-MeI; HOBT / DMAP / ethanol; CH₂Cl₂ / 18 h / 20 °C

With sodium dihydrogenphosphate; tritium; 2-methyl-but-2-ene; 4-carboxybenzophenone; 3-{[(ethylimino)methylene]-amino}-N,N,N-trimethyl-1-propanaminium iodide; benzotriazol-1-ol; dmap; In tetrahydrofuran; ethanol; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;

DOI:10.1021/ol0520166

Reference yield:

(4-hydroxymethyl-phenyl)-(4-iodo-phenyl)-methanone (870646-23-4) → C71H119(3)HO10Si4 (870646-25-6)

Guidance literature:

Multi-step reaction with 4 steps

1: 77 percent / NaHCO₃; Dess-Martin periodinane / CH₂Cl₂ / 5 h

2: 79 percent / 2-methyl-2-butene; NaH₂PO₄; NaOCl₂ / 2-methyl-propan-2-ol; tetrahydrofuran; H₂O / 18 h

3: tritium gas / dimethylformamide

4: 8.6 mg / 4-benzoylbenzoic acid; EDCI-MeI; HOBT / DMAP / ethanol; CH₂Cl₂ / 18 h / 20 °C

With sodium dihydrogenphosphate; tritium; 2-methyl-but-2-ene; 4-carboxybenzophenone; sodium hydrogencarbonate; 3-{[(ethylimino)methylene]-amino}-N,N,N-trimethyl-1-propanaminium iodide; benzotriazol-1-ol; Dess-Martin periodane; dmap; In tetrahydrofuran; ethanol; dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol; 1: Dess-Martin oxidation;

DOI:10.1021/ol0520166

Reference yield:

4-(4-iodobenzoyl)benzoic acid (870646-14-3) → C71H119(3)HO10Si4 (870646-25-6)

Guidance literature:

Multi-step reaction with 2 steps

1: tritium gas / dimethylformamide

2: 8.6 mg / 4-benzoylbenzoic acid; EDCI-MeI; HOBT / DMAP / ethanol; CH₂Cl₂ / 18 h / 20 °C

With tritium; 4-carboxybenzophenone; 3-{[(ethylimino)methylene]-amino}-N,N,N-trimethyl-1-propanaminium iodide; benzotriazol-1-ol; dmap; In ethanol; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1021/ol0520166

upstream raw materials:

4-(4-iodo-benzoyl)-benzaldehyde

(4-hydroxymethyl-phenyl)-(4-iodo-phenyl)-methanone

4-(4-iodobenzoyl)benzoic acid

[4-(tert-butyl-dimethyl-silanyloxymethyl)-phenyl]-(4-iodo-phenyl)-methanol