1,2-diallyl sulfanyl-1H-benzoimidazole

Base Information

• Chemical Name: 1,2-diallyl sulfanyl-1H-benzoimidazole
• CAS No.: 124530-69-4
• Molecular Formula: C₁₃H₁₄N₂S
• Molecular Weight: 230.334
• Mol file: 124530-69-4.mol

Synonyms:1,2-diallyl sulfanyl-1H-benzoimidazole

Chemical Property of 1,2-diallyl sulfanyl-1H-benzoimidazole

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1,2-diallyl sulfanyl-1H-benzoimidazole

There total 2 articles about 1,2-diallyl sulfanyl-1H-benzoimidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

allyl bromide (106-95-6) + Benzimidazol-2-thiol (134469-07-1) → 2-(allylthio)-1H-benzimidazole (51389-04-9) + 1,2-diallyl sulfanyl-1H-benzoimidazole (124530-69-4)

Guidance literature:

With reconstructed hydrotalcite; In ethanol; at 70 ℃; for 3h; Reagent/catalyst; Microwave irradiation; Cooling;

DOI:10.1055/s-0033-1339763

Reference yield: 37.0%

2-(allylthio)-1H-benzimidazole (51389-04-9) + chloroform (67-66-3,8013-54-5) → 2-(allylthio)benzo[d]oxazole (50463-17-7) + diallyl disulphide (2179-57-9) + 1,2-diallyl sulfanyl-1H-benzoimidazole (124530-69-4) + 2-(1,1-dichloro-3-butenylthio)benzimidazole

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; at 45 - 55 ℃; for 18h; Further byproducts given;

DOI:10.1007/BF02283553

Reference yield: 92.0%

1,2-diallyl sulfanyl-1H-benzoimidazole (124530-69-4) → 3-allylbenzimidazoline-2-thione (87216-53-3)

Guidance literature:

With sodium naphthalenide; In tetrahydrofuran; Ambient temperature;

upstream raw materials:

2-(allylthio)-1H-benzimidazole

chloroform

allyl bromide

Benzimidazol-2-thiol

Downstream raw materials:

3-allylbenzimidazoline-2-thione

Refernces

• 1、 Cruz-Gonzalez, Deysi Y.,González-Olvera, Rodrigo,Angeles-Beltrán, Deyanira,Negrón-Silva, Guillermo E.,Santillan, Rosa. "The activity of magnesium/aluminum 'memory effect' reconstructed hydrotalcites in the microwave-assisted synthesis of 2-benzimidazolethiol and its alkylated derivatives". . p. 3281 - 3287. Retrieved 2013/12/04.