(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane

Base Information

• Chemical Name: (S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane
• CAS No.: 911201-41-7
• Molecular Formula: C₃₃H₂₅P
• Molecular Weight: 452.535
• Mol file: 911201-41-7.mol

Synonyms:(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane

Chemical Property of (S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane

There total 1 articles about (S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane oxide → (S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane (911201-41-7)

Guidance literature:

With trichlorosilane; In toluene; at 90 ℃; for 18h;

DOI:10.1002/chem.200501470

Reference yield: 97.0%

(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane (911201-41-7) + chlorobis(cyclooctene)-iridium(I) dimer + silver trifluoromethanesulfonate (2923-28-6) → [Ir(S-(Ph)tropp(Ph))2]OTf

Guidance literature:

(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane; chlorobis(cyclooctene)-iridium(I) dimer; In tetrahydrofuran; for 1h;

silver trifluoromethanesulfonate; In tetrahydrofuran; for 5h;

Reference yield: 93.0%

(S)-(10-phenyl-5H-dibenzo[a,d]cyclohepten-5-yl)diphenylphosphane (911201-41-7) + chlorobis(ethylene)rhodium(I) dimer → [Rh2(μ2-Cl)2(S-(Ph)tropp(Ph))2]

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;