(4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

Base Information

Chemical Name:(4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate
CAS No.:1196033-54-1
Molecular Formula:C₂₀H₂₄O₇
Molecular Weight:376.406
Hs Code.:

Synonyms:(4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

Suppliers and Price of (4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

There total 1 articles about (4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15795-51-4
2,2-dimethyl-5-(4-methylbenzylidene)-1,3-dioxane-4,6-dione

: 1007392-16-6
ethyl [(E)-3-(1,1,1-tributylstannyl)-2-propenyl] carbonate

: (4S,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

: 1196033-54-1
(4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

Guidance literature:: With silver hexafluoroantimonate; chlorobis(ethylene)rhodium(I) dimer; 5-methoxy-1,5-dimethyl-2-(2-(trifluoromethyl)phenyl)bicyclo[2.2.2]octa-2,7-diene; In tetrahydrofuran; at 10 ℃; for 45h; optical yield given as %ee; enantioselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1021/ol902216y

Reference yield:

: 64-17-5
ethanol

: 1196033-54-1
(4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate

: 1196033-64-3
(3S,4E)-ethyl 6-hydroxy-3-p-tolylhex-4-enoate

Guidance literature:: ethanol; (4R,2E)-4-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-4-p-tolylbut-2-enyl ethyl carbonate; With pyridine; copper; for 3.5h; Inert atmosphere; Reflux;

With potassium carbonate; In ethanol; at 20 ℃; for 18h; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol902216y