(η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

Base Information

Chemical Name:(η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel
CAS No.:265651-54-5
Molecular Formula:C₂₇H₃₂N₂Ni
Molecular Weight:443.254
Hs Code.:

Synonyms:(η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

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Chemical Property of (η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

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Technology Process of (η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

There total 1 articles about (η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 265651-53-4
chloro(η⁵-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)nickel(II)

: 917-54-4
methyllithium

: 265651-54-5
(η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

Guidance literature:: In tetrahydrofuran; diethyl ether; byproducts: LiCl; under Ar; MeLi in Et2O was added dropwise to stirred soln of Ni-complex in THF at -78°C, mixt. was allowed to warm slowly to ambient temp.; solvent and volatiles were removed under reduced pressure, residue was extracted with hexane, filtered, filtrate was reduced in vol., storage for 2 d at -30°C, filtered, dried in vacuo; elem. anal.;
DOI:10.1016/S0022-328X(99)00557-4

Reference yield: 71.0%

: 265651-54-5
(η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel

: 19393-11-4
potassium acetylacetonate

: C₂₇H₃₄N₂NiO₂

Guidance literature:: (η5-cyclopentadienyl)(1,3-dimesitylimidazol-2-ylidene)methylnickel; With potassium hexafluorophosphate; hydrogenchloride; In water; acetonitrile; at 20 ℃; for 0.166667h; Inert atmosphere;

potassium acetylacetonate; In water; acetonitrile; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1039/c3cc43691h