(+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

Base Information

Chemical Name:(+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione
CAS No.:111795-56-3
Molecular Formula:C₁₀H₁₃N₅O₄
Molecular Weight:267.244
Hs Code.:

Synonyms:(+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

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Chemical Property of (+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

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Technology Process of (+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

There total 1 articles about (+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59967-83-8
(+/-)-1-<(1β,2α,3α,4β)-2,3-dihydroxy-4-(hydroxymethyl)cyclopentyl>-2,4-(1H,3H)-pyrimidinedione

: 111795-56-3
(+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

Guidance literature:: Multi-step reaction with 2 steps

1: 67 percent / NaHCO₃ / dimethylformamide; various solvent(s) / 0.5 h / 150 °C

2: 45 percent / LiN₃ / hexamethylphosphoric acid triamide / 150 °C

With lithium azide; sodium hydrogencarbonate; In N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1021/jm00397a038

Reference yield:

: 111795-56-3
(+/-)-(1α,2β,3β,4α)-1-<2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2,4(1H,3H)-pyrimidinedione

: 111795-59-6
(+/-)-4-amino-1-<(1α,2β,3β,4α)-2-azido-3-hydroxy-4-(hydroxymethyl)cyclopentyl>-2(1H)-pyrimidinone

Guidance literature:: Multi-step reaction with 3 steps

1: Py / 24 h / Ambient temperature

2: 61 percent / p-ClC₆H₄OPOCl₂, Py / 72 h / Ambient temperature

3: 1.) NH₂OH, 2.) NH₃ / 1.) dioxane, room temperature, 4 h, 2.) MeOH

With pyridine; ammonia; hydroxylamine; 4-chlorophenylphosphorodichloridate;
DOI:10.1021/jm00397a038