benzyl N-[(S)-2-vinylferrocenyl]carbamate

Base Information

Chemical Name:benzyl N-[(S)-2-vinylferrocenyl]carbamate
CAS No.:875768-23-3
Molecular Formula:C₂₀H₁₉FeNO₂
Molecular Weight:361.223
Hs Code.:

Synonyms:benzyl N-[(S)-2-vinylferrocenyl]carbamate

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Chemical Property of benzyl N-[(S)-2-vinylferrocenyl]carbamate

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Technology Process of benzyl N-[(S)-2-vinylferrocenyl]carbamate

There total 1 articles about benzyl N-[(S)-2-vinylferrocenyl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 875768-21-1
(1S)-1-carboxyl-2-vinylferrocene

: 26386-88-9
diphenyl phosphoryl azide

: 100-51-6,185532-71-2
benzyl alcohol

: 875768-23-3
benzyl N-[(S)-2-vinylferrocenyl]carbamate

Guidance literature:: With triethylamine; In toluene; byproducts: N2; under N2 or Ar, Schlenk technique; dry Et3N and Ph2PON3 successively added to soln. of Fe complex in toluene, mixt. stirred for 20 min, quickly heated to 95°C, PhCH2OH added after 40 min, stirred at 95°C for 5 min, cooled to room temp.; extd. with MeOCMe3/H2O, organic phase sepd. and dried over MgSO4, filtrate evapd., residue filtered over passivated Al2O3 (basic, activity II); elem. anal.;
DOI:10.1021/om050845p

Reference yield: 83.0%

: 875768-23-3
benzyl N-[(S)-2-vinylferrocenyl]carbamate

: 829-85-6
diphenylphosphane

: benzyl N-[(S)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocenyl]carbamate

Guidance literature:: In acetic acid; under N2 or Ar, Schlenk technique; 4 equiv. of P(C6H5)2H added to soln. of Fe complex in dry acetic acid at room temp., mixt. stirred at 65°C for 16 h; evapd. under vac., residue washed with pentane and recrystd. from isopropanol; elem. anal.;
DOI:10.1021/om050845p

Reference yield: 82.0%

: 67-51-6
3,5-dimethyl-1H-pyrazole

: 875768-23-3
benzyl N-[(S)-2-vinylferrocenyl]carbamate

: benzyl N-[(S)-2-[(1R)-1-(3,5-dimethylpyrazol-1-yl)ethyl]ferrocenyl]carbamate

Guidance literature:: In acetic acid; under N2 or Ar; 5 equiv. of 3,5-dimethylpyrazole added to soln. of Fe complex in dry acetic acid at room temp., mixt. stirred at 60°C for105 min; evapd. under vac., column chromy. (silica gel, hexane/ethyl acetate/Et3N(10/1/0.05));
DOI:10.1021/om050845p