((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

Base Information

Chemical Name:((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium
CAS No.:79643-31-5
Molecular Formula:C₂₁H₁₁O₆Re
Molecular Weight:545.522
Hs Code.:

Synonyms:((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

Suppliers and Price of ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

There total 1 articles about ((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 14971-38-1,35725-77-0
pentacarbonylrhenium^(1-)

: 6415-58-3
2,3-diphenyl-2-cyclopropene-1-carbonyl chloride

: 79643-31-5
((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

Guidance literature:: In tetrahydrofuran; acyl chloride reacted with Re(CO)5(1-) in THF at -78°C, followedwarming to -20°C; solvent removed at -20°C, recrystd.;
DOI:10.1021/ja00408a063

Reference yield: 51.0%

: 79643-31-5
((2,3-diphenyl-2-cyclopropen-1-yl)carbonyl)pentacarbonylrhenium

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 79643-33-7
(3-η1-2,3-diphenylcyclopropenyl)pentacarbonylrhenium

Guidance literature:: In chloroform-d1; Re-complex was dissolved in CDCl3, allowed to stand at 20°C under N2 for 4 h; evapd. to dryness, chromd. on silica gel/hexane column, eluted with hexane, then benzene, evapd., recrystd. from hexane;
DOI:10.1021/ja00382a018