methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Base Information

Chemical Name:methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside
CAS No.:166769-06-8
Molecular Formula:C₆₂H₅₄Br₄O₁₅
Molecular Weight:1358.72
Hs Code.:

Synonyms:methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

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Chemical Property of methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

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Technology Process of methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

There total 4 articles about methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 4356-80-3,34212-64-1,40653-32-5,53008-65-4,55094-38-7,68027-27-0,73111-53-2,128184-63-4,138794-99-7,641635-63-4
methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside

: 123505-65-7
2,3,4,6-Tetrakis-O-(p-bromobenzoyl)-α-D-glucopyranosyl bromide

: 166769-06-8
methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With silver trifluoromethanesulfonate; tetramethylurea; In dichloromethane; at -40 ℃; for 0.5h;
DOI:10.1021/jo026913o

Reference yield:

: 143249-53-0
methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside

: 166769-06-8
methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 40 percent / NaH / dimethylformamide

2: 81 percent / Bu₄NF*3H₂O / tetrahydrofuran / 12 h / 20 °C

3: 92 percent / TMU; AgOTf / CH₂Cl₂ / 0.5 h / -40 °C

With tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; sodium hydride; tetramethylurea; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo026913o

Reference yield:

: 709-50-2
methyl beta-D-glucopyranoside

: 166769-06-8
methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / imidazole / dimethylformamide / 24 h

2: 40 percent / NaH / dimethylformamide

3: 81 percent / Bu₄NF*3H₂O / tetrahydrofuran / 12 h / 20 °C

4: 92 percent / TMU; AgOTf / CH₂Cl₂ / 0.5 h / -40 °C

With 1H-imidazole; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; sodium hydride; tetramethylurea; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo026913o