143249-53-0

Basic information

• Product Name: methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside
• Synonyms: methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside
• CAS NO: 143249-53-0
• Molecular Weight: 432.589
• Mol File: 143249-53-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(143249-53-0)
• EPA Substance Registry System: methyl 6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside(143249-53-0)

Safety Data

• Hazardous Substances Data: 143249-53-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 709-50-2 methyl beta-D-glucopyranoside 

Downstream Products

• 143249-57-4 Methyl O-(2,3,4-tri-O-benzoyl-6-O-bromoacetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-β-D-glucopyranoside 
• 143249-58-5 Methyl O-(2,3,4-tri-O-benzoyl-6-O-bromoacetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranoside 
• 143249-59-6 O-(2,3,4-Tri-O-benzoyl-6-O-bromoacetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-glucopyranosyl chloride 
• 88037-32-5 methyl 2,3,4-tri-O-benzoyl-β-D-glucopyranoside 
• 313055-91-3 C₃₁H₃₂O₉ 
• 556814-80-3 methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-acetyl-β-D-glucopyranoside 
• 556814-81-4 methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-acetyl-α-D-glucopyranoside 
• 166769-06-8 methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 166769-10-4 methyl 6-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-β-D-glucopyranoside 
• 4356-80-3 methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 155044-88-5 methyl 2,3,4-tri-O-benzyl-6-O-(tert-butyldiphenylsilyl)-β-D-glucopyranoside 
• 312700-94-0 C₄₇H₅₀O₉Si 
• 143249-54-1 Methyl 2,3,4-tri-O-benzoyl-6-O-tert-butyldiphenylsilyl-β-D-glucopyranoside 

Relevant articles and documents

Hydroxymethyl rotamer populations in disaccharides

Sixteen methyl glucopyranosyl glucopyranoside disaccharides (methyl β-D-Glcp(p-Br-Bz)-(1→x)-β/ α-D-Glcp) containing β-glycosidic linkages (1→2, 1→3, 1→4, and 1→6) were synthesized and analyzed by means of CD and NMR spectroscopy in three different solvent

Tandem epoxidation-alcoholysis or epoxidation-hydrolysis of glycals catalyzed by titanium(IV) isopropoxide or Venturello's phosphotungstate complex

Venturello's phosphotungstate complex and titanium(IV) isopropoxide [Ti(O-i-Pr)4] were successfully used as catalysts for the epoxidation-alcoholysis of glycals using hydrogen peroxide [H2O 2]. Reaction substrates included a range of variously protected glycals and different alcohols were used as solvents. Ti(O-i-Pr)4 was only effective in methanol as solvent, but gave methyl glycosides in high yields and high selectivities. The Venturello complex proved to be a very versatile and efficient catalyst. Apart from epoxidation-alcoholysis in alcoholic solvents it also showed activity in biphasic conditions to allow for glycosylation of long-chain alcohols and was very effective in the stereoselective dihydroxylation of benzylated glucal.

Binding studies on internal immunodeterminants: synthesis of β-(1->6)-linked oligosaccharide methyl glycosides having one to four internal D-galactopyranosyl residues flanked by gentiobiose residues

The oligosaccharide glycosides β-D-Glcp-(1->6)-β-D-Glcp-(1->6)-6)>n-β-D-Glcp-(1->6)-β-D-Glcp-1->OMe (n=1-4) were prepared by a convergent block synthesis.Haloacetyl, tert-butyldiphenylsilyl, and dimethylthexylsilyl groups were used as tempo