1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

Base Information

Chemical Name:1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione
CAS No.:116498-69-2
Molecular Formula:C₂₉H₃₀N₂O₆S₄
Molecular Weight:630.831
Hs Code.:

Synonyms:1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

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Chemical Property of 1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

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Technology Process of 1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

There total 4 articles about 1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 99270-82-3
1,3-dihydro-3-methyl-4-(4-thio-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

: 98-59-9
p-toluenesulfonyl chloride

: 116498-69-2
1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

Guidance literature:: With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90799-7

Reference yield:

: 116384-46-4
1,3-dihydro-3-methyl-4-(4-thio-D-arabino-tetritol-1-yl)-1-p-tolyl-2H-imidazole-2-thione

: 116498-69-2
1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

Guidance literature:: Multi-step reaction with 2 steps

1: trifluoroacetic acid / aq. ethanol / 3 h / Heating

2: 74 percent / tetrabutylammonium hydrogensulphate/5percent NaOH / CH₂Cl₂ / 2 h / Ambient temperature

With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate; trifluoroacetic acid; In ethanol; dichloromethane;
DOI:10.1016/S0008-6215(00)90799-7

Reference yield:

: 116384-45-3
1,3-dihydro-3-methyl-1-p-tolyl-(1,2,3-tri-O-acetyl-4-S-acetyl-4-thio-D-arabino-tetritol-1-yl)-2H-imidazole-2-thione

: 116498-69-2
1,3-dihydro-3-methyl-4-(4-thio-2,3-di-O-p-tolylsulphonyl-β-D-erythrofuranosyl)-1-p-tolyl-2H-imidazole-2-thione

Guidance literature:: Multi-step reaction with 3 steps

1: sodium methoxide / methanol / 0.08 h / Ambient temperature

2: trifluoroacetic acid / aq. ethanol / 3 h / Heating

3: 74 percent / tetrabutylammonium hydrogensulphate/5percent NaOH / CH₂Cl₂ / 2 h / Ambient temperature

With sodium hydroxide; sodium methylate; tetra(n-butyl)ammonium hydrogensulfate; trifluoroacetic acid; In methanol; ethanol; dichloromethane;
DOI:10.1016/S0008-6215(00)90799-7