Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆

Base Information

• Chemical Name: Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆
• CAS No.: 1129455-03-3
• Molecular Formula: C₂₇H₁₈ClN₄O₂Pt*F₆P
• Molecular Weight: 805.963
• Mol file: 1129455-03-3.mol

Synonyms:Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆

Chemical Property of Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆

Chemical Property:

Purity/Quality:

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Technology Process of Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆

There total 1 articles about Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

ammonium hexafluorophosphate + dichlorobis(dimethyl sulfoxide)platinum(II) + 4'-(4-m-nitrophenyl-phenyl)-2,2':6',2'-terpyridine (1129454-97-2) → Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF6 (1129455-03-3)

Guidance literature:

In acetonitrile; (under N2); ligand mixed with Pt-complex in MeCN, stirred at 80°Cfor 48 h, NH4PF6 added, H2O added, stirred for 15 min; filtered, washed with CHCl3 and ether;

DOI:10.1021/ic801769v

Reference yield: 80.0%

N-(4-ethynyl-benzyl)phenothiazine (362682-20-0) + Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF6 (1129455-03-3) → [Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)(4-ethynylbenzyl-N-phenothiazine)]PF6 (1129454-93-8)

Guidance literature:

With triethylamine; copper(l) iodide; In N,N-dimethyl-formamide; (under N2); Pt-complex, CuI, ligand and DMF mixed, triethylamine added, stirred in dark for 48 h, treated with Et2O; filtered, washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1021/ic801769v

Reference yield: 62.0%

Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)ClPF6 (1129455-03-3) + phenylacetylene (536-74-3) → [Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)C2C6H5]PF6 (1129454-86-9)

Guidance literature:

With triethylamine; copper(l) iodide; In N,N-dimethyl-formamide; (under N2); Pt-complex, CuI and DMF mixed, phenylacetylene added, triethylamine added, stirred in dark for 48 h, treated with Et2O; filtered, washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1021/ic801769v

upstream raw materials:

4'-(4-m-nitrophenyl-phenyl)-2,2':6',2'-terpyridine

Downstream raw materials:

[Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)(4-ethynylbenzyl-N-phenothiazine)]PF₆

[Pt(4'-(4-m-nitrophenyl-phenyl)-2,2':6',2''-terpyridine)C₂C₆H₅]PF₆