((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

Base Information

Chemical Name:((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide
CAS No.:1333237-00-5
Molecular Formula:C₃₇H₄₈O₂PSi*I
Molecular Weight:710.751
Hs Code.:

Synonyms:((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

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Chemical Property of ((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

Chemical Property:

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Technology Process of ((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

There total 7 articles about ((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 1333236-98-8
((2S,3R)-3-(benzyloxy)-6-iodohexan-2-yloxy)(tert-butyl)dimethylsilane

: 603-35-0
triphenylphosphine

: 1333237-00-5
((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

Guidance literature:: In benzene; for 42h; Reflux; Inert atmosphere;
DOI:10.1002/anie.201102521

Reference yield:

: 1333236-95-5
(4R,5S)-4-(benzyloxy)-5-[(tert-butyldimethylsilyl)oxy]hexan-1-ol

: 1333237-00-5
((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole; iodine; triphenylphosphine / benzene / 13.5 h / 20 °C / Darkness; Inert atmosphere

2: benzene / 42 h / Reflux; Inert atmosphere

With 1H-imidazole; iodine; triphenylphosphine; In benzene;
DOI:10.1002/anie.201102521

Reference yield:

: 1333236-84-2
(5S,6R)-2,2,3,3,5,11,11,12,12-nonamethyl-4,10-dioxa-3,11-disilatridecan-6-ol

: 1333237-00-5
((4R,5S)-4-(benzyloxy)-5-(tert-butyldimethylsilyloxy)hexyl)triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 4 steps

1: tetra-(n-butyl)ammonium iodide; sodium hydride / N,N-dimethyl-formamide / 18 h / 0 - 20 °C / Inert atmosphere

2: pyridine; pyridine hydrofluoride / tetrahydrofuran / 1.25 h / 0 °C / Inert atmosphere

3: 1H-imidazole; iodine; triphenylphosphine / benzene / 13.5 h / 20 °C / Darkness; Inert atmosphere

4: benzene / 42 h / Reflux; Inert atmosphere

With pyridine; 1H-imidazole; pyridine hydrofluoride; iodine; tetra-(n-butyl)ammonium iodide; sodium hydride; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide; benzene;
DOI:10.1002/anie.201102521