1,1'-dimethylcobaltocenium hexafluorophosphate

Base Information

• Chemical Name: 1,1'-dimethylcobaltocenium hexafluorophosphate
• CAS No.: 33638-88-9
• Molecular Formula: C₁₂H₁₄Co*F₆P
• Molecular Weight: 362.201
• Mol file: 33638-88-9.mol

Synonyms:1,1'-dimethylcobaltocenium hexafluorophosphate

Chemical Property of 1,1'-dimethylcobaltocenium hexafluorophosphate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 1,1'-dimethylcobaltocenium hexafluorophosphate

There total 1 articles about 1,1'-dimethylcobaltocenium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium hexaflorophosphate + methylcyclopentadiene (96-38-8) + cobalt(II) bromide → bis(cyclopentadienyl)cobalt(III) hexafluorophosphate (12427-42-8) + methylcobaltocenium hexafluorophosphate + 1,1'-dimethylcobaltocenium hexafluorophosphate (33638-88-9)

Guidance literature:

In not given; addn. of anhydrous CoBr2 in small portions to a soln. of C5H5CH3 at 0 °C, react. for 12 h at room temp., evapg., dissolving the residue in hot H2O, extg. with ether, addn. of NaPF6 to the aq. soln.;; pptn., sepn. of product mixt. by recrystn. or chromy. was not possible;;

DOI:10.1021/jo00835a014

Reference yield:

tetraphenylborate anion (4358-26-3) + 1,1'-dimethylcobaltocenium hexafluorophosphate (33638-88-9) → {Co(C5H4COOH)2}(1+)*B(C6H5)4(1-)={Co(C5H4COOH)2}B(C6H5)4

Guidance literature:

With sodium hydroxide; potassium permanganate; In water; oxidation at 95 - 100°C;; pptn. as B(C6H5)4 salt;;

upstream raw materials:

methylcyclopentadiene