dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Base Information

Chemical Name:dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside
CAS No.:1577227-84-9
Molecular Formula:C₆₀H₇₅N₃O₁₇Si
Molecular Weight:1138.35
Hs Code.:

dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Synonyms:dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Suppliers and Price of dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

There total 8 articles about dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 1577227-85-0
C₃₉H₄₀Cl₃NO₁₂

: dimethylthexylsilyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside

: 1577227-84-9
dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Guidance literature:: C₃₉H₄₀Cl₃NO₁₂; dimethylthexylsilyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranoside; In dichloromethane; toluene; at 20 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With trifluorormethanesulfonic acid; In tetrahydrofuran; toluene; at -30 ℃; Molecular sieve; Inert atmosphere;
DOI:10.1039/c3ob42312c

Reference yield:

: 1577227-74-7
dimethylthexylsilyl O-methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-β-D-glucopyranosyluronate

: 1577227-84-9
dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: dmap / dichloromethane / 20 °C / Inert atmosphere

2.1: pyridine hydrogenfluoride / tetrahydrofuran / 18 h / Inert atmosphere

3.1: sodium hydride / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

4.1: dichloromethane; toluene / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

4.2: -30 °C / Molecular sieve; Inert atmosphere

With dmap; sodium hydride; pyridine hydrogenfluoride; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1039/c3ob42312c

Reference yield:

: 1577227-58-7
dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside

: 1577227-84-9
dimethylthexylsilyl O-(methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate)-(1→4)-O-2-deoxy-2-azido-3-O-benzyl-6-O-acetyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1.1: pyridine; dmap / 4 h / 0 - 20 °C / Inert atmosphere

2.1: ethanethiol; toluene-4-sulfonic acid / dichloromethane; water / 1 h / 20 °C / Inert atmosphere

3.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C / Inert atmosphere

3.2: Inert atmosphere

4.1: dmap / dichloromethane / 20 °C / Inert atmosphere

5.1: pyridine hydrogenfluoride / tetrahydrofuran / 18 h / Inert atmosphere

6.1: sodium hydride / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

7.1: dichloromethane; toluene / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

7.2: -30 °C / Molecular sieve; Inert atmosphere

With pyridine; dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; sodium hydride; toluene-4-sulfonic acid; pyridine hydrogenfluoride; ethanethiol; In tetrahydrofuran; dichloromethane; water; toluene;
DOI:10.1039/c3ob42312c