dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside

Base Information

• Chemical Name: dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside
• CAS No.: 1577227-58-7
• Molecular Formula: C₂₈H₄₀O₆Si
• Molecular Weight: 500.707
• Mol file: 1577227-58-7.mol

Synonyms:dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside

Chemical Property of dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside

There total 1 articles about dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

chlorodimethyl(1,1,2-trimethylpropyl)silane (67373-56-2) + 3-O-benzyl-4,6-O-benzylidene-α/β-D-glucopyranose → dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside (1577227-58-7)

Guidance literature:

With 1H-imidazole; In dichloromethane; at 20 ℃; for 10h;

DOI:10.1039/c6ob00655h

Reference yield: 91.0%

dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside (1577227-58-7) → dimethylthexylsilyl 3,4-O-benzyl-β-D-glucopyranoside (1577228-10-4)

Guidance literature:

dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside; In dichloromethane; at 20 ℃; for 1h; Molecular sieve; Inert atmosphere;

With triethylsilane; phenylborondichloride; In dichloromethane; at -78 ℃; for 1h; Molecular sieve; Inert atmosphere;

With triethylamine; In methanol; dichloromethane; Molecular sieve; Inert atmosphere;

DOI:10.1039/c3ob42312c

Reference yield: 90.0%

dimethylthexylsilyl 3-O-benzyl-4,6-di-O-benzylidene-β-D-glucopyranoside (1577227-58-7) + levulinic acid (123-76-2) → dimethylthexylsilyl 2-O-levulinoyl-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside (1577227-60-1)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c3ob42312c

upstream raw materials:

chlorodimethyl(1,1,2-trimethylpropyl)silane

Downstream raw materials:

dimethylthexylsilyl O-methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-β-D-glucopyranosyluronate

dimethylthexylsilyl O-methyl-2-O-acetyl-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate

dimethylthexylsilyl O-methyl-2-O-levulinoyl-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate

dimethylthexylsilyl O-methyl-2-O-(4-acetoxy-2,2-dimethylbutanoate)-3-O-benzyl-4-O-(9-fluorenylmethoxycarbonyl)-β-D-glucopyranosyluronate