bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

Base Information

Chemical Name:bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate
CAS No.:351195-58-9
Molecular Formula:C₅₂H₄₆N₄O₁₀
Molecular Weight:886.958
Hs Code.:

Synonyms:bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

Suppliers and Price of bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

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Technology Process of bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

There total 4 articles about bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 20246-81-5
4,4'-dinitrodiphenic acid

: 111232-16-7
4'-[(6-hydroxyhexyl)oxy]biphenyl-4-carbonitrile

: 351195-58-9
bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1021/ja0042682

Reference yield:

: 629-11-8
1,6-hexanediol

: 351195-58-9
bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 42 percent / HBr; H₂SO₄ / H₂O / 2 h / Heating

2: 92 percent / K₂CO₃ / acetone / 24 h / Heating

3: 76 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

With dmap; sulfuric acid; hydrogen bromide; potassium carbonate; dicyclohexyl-carbodiimide; In dichloromethane; water; acetone;
DOI:10.1021/ja0042682

Reference yield:

: 4286-55-9
1-bromo-6-hexanol

: 351195-58-9
bis{ω-[4-(4-cyanophenyl)phenoxy]hexyl}4,4'-dinitro-biphenyl-2,2'-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / K₂CO₃ / acetone / 24 h / Heating

2: 76 percent / DCC; DMAP / CH₂Cl₂ / 24 h / 20 °C

With dmap; potassium carbonate; dicyclohexyl-carbodiimide; In dichloromethane; acetone;
DOI:10.1021/ja0042682