C₃₆H₇₀O₅Si₂

Base Information

• Chemical Name: C₃₆H₇₀O₅Si₂
• CAS No.: 1337552-82-5
• Molecular Formula: C₃₆H₇₀O₅Si₂
• Molecular Weight: 639.12
• Mol file: 1337552-82-5.mol

Synonyms:C₃₆H₇₀O₅Si₂

Chemical Property of C₃₆H₇₀O₅Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₆H₇₀O₅Si₂

There total 18 articles about C₃₆H₇₀O₅Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

C36H68O5Si2 (1337552-81-4) → C36H70O5Si2 (1337552-82-5)

Guidance literature:

With acetic acid; tetramethylammonium triacetoxyborohydride; In acetonitrile; at -20 ℃; for 48h;

DOI:10.1016/j.tetlet.2011.07.105

Reference yield:

(S)-4-benzyl-3-((S)-2-methylhexanoyl)oxazolidin-2-one (177607-70-4) → C36H70O5Si2 (1337552-82-5)

Guidance literature:

Multi-step reaction with 11 steps

1.1: methanol; lithium borohydride / diethyl ether / 6 h / 20 °C

2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane / 20 h / 20 °C

3.1: (+)-Ipc₂BOMe / diethyl ether / 3 h / -78 - 20 °C

4.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C

5.1: ozone / dichloromethane / 1 h / -78 °C

5.2: 6 h / 20 °C

6.1: diethyl ether / 4 h / -78 °C

7.1: pyridine; Dess-Martin periodane / dichloromethane / 15 h / 20 °C

8.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / 40 °C

9.1: (triphenylphosphine)copper(I) hydride hexamer; phenylsilane / toluene / 24 h / 20 °C

10.1: methanol; pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C

11.1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / 48 h / -20 °C

With pyridine; 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; methanol; dmap; lithium borohydride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; (triphenylphosphine)copper(I) hydride hexamer; [bis(acetoxy)iodo]benzene; phenylsilane; pyridinium p-toluenesulfonate; Dess-Martin periodane; ozone; acetic acid; tetramethylammonium triacetoxyborohydride; In diethyl ether; dichloromethane; toluene; acetonitrile;

DOI:10.1016/j.tetlet.2011.07.105

Reference yield:

S-(+)-2-methylhexanal (66875-71-6) → C36H70O5Si2 (1337552-82-5)

Guidance literature:

Multi-step reaction with 9 steps

1.1: (+)-Ipc₂BOMe / diethyl ether / 3 h / -78 - 20 °C

2.1: 1H-imidazole; dmap / dichloromethane / 12 h / 20 °C

3.1: ozone / dichloromethane / 1 h / -78 °C

3.2: 6 h / 20 °C

4.1: diethyl ether / 4 h / -78 °C

5.1: pyridine; Dess-Martin periodane / dichloromethane / 15 h / 20 °C

6.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / 40 °C

7.1: (triphenylphosphine)copper(I) hydride hexamer; phenylsilane / toluene / 24 h / 20 °C

8.1: methanol; pyridinium p-toluenesulfonate / dichloromethane / 0.5 h / 20 °C

9.1: acetic acid; tetramethylammonium triacetoxyborohydride / acetonitrile / 48 h / -20 °C

With pyridine; 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; methanol; dmap; (triphenylphosphine)copper(I) hydride hexamer; phenylsilane; pyridinium p-toluenesulfonate; Dess-Martin periodane; ozone; acetic acid; tetramethylammonium triacetoxyborohydride; In diethyl ether; dichloromethane; toluene; acetonitrile;

DOI:10.1016/j.tetlet.2011.07.105

upstream raw materials:

C₂₇H₅₀O₃Si₂

C₂₁H₃₆O₃Si

C₁₆H₃₄OSi

C₁₀H₂₀O

Downstream raw materials:

C₃₉H₇₄O₅Si₂

Refernces