66875-71-6

Basic information

• Product Name: Hexanal, 2-methyl-, (2S)-
• CAS NO: 66875-71-6
• Molecular Formula: C7H14O
• Molecular Weight: 114.188
• Mol File: 66875-71-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Hexanal, 2-methyl-, (2S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hexanal, 2-methyl-, (2S)-(66875-71-6)
• EPA Substance Registry System: Hexanal, 2-methyl-, (2S)-(66875-71-6)

Safety Data

• Hazardous Substances Data: 66875-71-6(Hazardous Substances Data)

Upstream product

• 592-41-6 1-hexene 
• 201230-82-2 carbon monoxide 
• 19710-56-6 hydroxycarbene 

Downstream Products

• 609-14-3 2-acetylpropanoic acid ethyl ester 
• 1337552-55-2 C₃₉H₇₄O₅Si₂ 
• 1337552-82-5 C₃₆H₇₀O₅Si₂ 
• 1337552-81-4 C₃₆H₆₈O₅Si₂ 
• 1337552-79-0 C₄₂H₈₂O₅Si₃ 
• 1337552-69-8 C₄₂H₈₀O₅Si₃ 

Relevant articles and documents

An asymmetric hydroformylation catalyst that delivers branched aldehydes from alkyl alkenes

Surprising selectivity: The first enantioselective hydroformylations of simple alkenes of type RCH2CH=CH2 to preferentially deliver the branched aldehyde product have been discovered using a new chiral ligand, named bobphos (see scheme). Established ligands are unselective in this reaction or show a slight preference towards the linear aldehyde. Copyright

Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities

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Asymmetric hydroformylation catalyzed by an Rh( I) -( R,S) -BINAPHOS complex: Substituent effects in olefins on the regioselectivity

Olefins bearing the larger substituants at the allylic position were hydroformylated in the higher iso/normal selectivity when Rh(I)-(R,S)-BINAPHOS was used as a catalyst. Deuterioformylation of 4,4,4-triphenyl-1 -butene suggests that the higher iso/normal ratio may be attributed to the accelerated CO insertion to the iso-alkylrhodium 7i.