methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate

Base Information

• Chemical Name: methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate
• CAS No.: 1226792-41-1
• Molecular Formula: C₂₀H₂₇NO₃Se
• Molecular Weight: 408.399
• Mol file: 1226792-41-1.mol

Synonyms:methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate

Chemical Property of methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate

There total 1 articles about methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

Phenylselenyl chloride (5707-04-0) + methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxopropanoate (1226792-86-4) → methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate (1226792-41-1)

Guidance literature:

methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxopropanoate; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.333333h;

Phenylselenyl chloride; In tetrahydrofuran; mineral oil; at -78 - 20 ℃; for 4h; optical yield given as %de;

DOI:10.1021/jo100139u

Reference yield: 84.0%

methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxo-2-(phenylseleno)propanoate (1226792-41-1) → methyl cis-1-tert-butyl-2-oxo-cis-4-(phenylseleno)-octahydro-1H-indole-cis-3-carboxylate

Guidance literature:

With ytterbium(III) triflate; In diethyl ether; at -78 - 20 ℃; stereoselective reaction; Inert atmosphere; UV-irradiation;

DOI:10.1021/jo100139u

upstream raw materials:

Phenylselenyl chloride

methyl 3-(t-butyl(cyclohex-2-enyl)amino)-3-oxopropanoate