C₆₀H₃₇N₅O₂Zn

Base Information

• Chemical Name: C₆₀H₃₇N₅O₂Zn
• CAS No.: 1548367-79-8
• Molecular Formula: C₆₀H₃₇N₅O₂Zn
• Molecular Weight: 925.376
• Mol file: 1548367-79-8.mol

Synonyms:C₆₀H₃₇N₅O₂Zn

Chemical Property of C₆₀H₃₇N₅O₂Zn

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₀H₃₇N₅O₂Zn

There total 5 articles about C₆₀H₃₇N₅O₂Zn which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

C38H23BrN4Zn (162479-04-1) + 4,4'-(4-ethynylphenylazanediyl)dibenzaldehyde (1548367-68-5) → C60H37N5O2Zn (1548367-79-8)

Guidance literature:

C₃₈H₂₃BrN₄Zn; 4,4'-(4-ethynylphenylazanediyl)dibenzaldehyde; With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; tetrabutyl ammonium fluoride; for 0.166667h; Inert atmosphere;

With triethylamine; In tetrahydrofuran; at 20 ℃; for 20h;

DOI:10.1021/jo402658h

Reference yield:

4,4'-(4-((trimethylsilyl)ethynyl)phenylazanediyl)dibenzaldehyde (1548367-66-3) → C60H37N5O2Zn (1548367-79-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetrabutyl ammonium fluoride / dichloromethane; tetrahydrofuran / 0.5 h / 0 °C

2.1: tetrabutyl ammonium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane / 0.17 h / Inert atmosphere

2.2: 20 h / 20 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; tetrabutyl ammonium fluoride; In tetrahydrofuran; dichloromethane; 2.1: |Heck Reaction;

DOI:10.1021/jo402658h

Reference yield:

4,4'-diformyltriphenylamine (53566-95-3) → C60H37N5O2Zn (1548367-79-8)

Guidance literature:

Multi-step reaction with 4 steps

1.1: iodine; silver(II) sulfate

2.1: trans-bis(triphenylphosphine)palladium dichloride; copper(l) iodide; triethylamine / tetrahydrofuran / 17 h / -196.16 - 19.84 °C / Inert atmosphere

3.1: tetrabutyl ammonium fluoride / dichloromethane; tetrahydrofuran / 0.5 h / 0 °C

4.1: tetrabutyl ammonium fluoride; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane / 0.17 h / Inert atmosphere

4.2: 20 h / 20 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; silver(II) sulfate; trans-bis(triphenylphosphine)palladium dichloride; triphenyl-arsane; tetrabutyl ammonium fluoride; iodine; triethylamine; In tetrahydrofuran; dichloromethane; 2.1: |Sonogashira Cross-Coupling / 4.1: |Heck Reaction;

DOI:10.1021/jo402658h

upstream raw materials:

4,4'-(4-((trimethylsilyl)ethynyl)phenylazanediyl)dibenzaldehyde

C₃₈H₂₃BrN₄Zn

4,4'-(4-ethynylphenylazanediyl)dibenzaldehyde

N,N-diphenylaminobenzene