162479-04-1Relevant articles and documents
Bisporphyrin connected by pyrimidine: Synthesis and photo physical properties
Achelle, Sylvain,Saettel, Nicolas,Baldeck, Patrice,Fichou, Marie-Paule Teulade,Maillard, Philippe
, p. 877 - 884 (2010)
We report the synthesis of a series of zinc porphyrins conjugated with pyrimidine derivatives. V shaped porphyrin dimer with a pyrimidine central core exhibits a planar geometry according to DFT computational studies, presents an internal charge transfer upon excitation proved by typical solvatochromic behavior and moderate two-photon absorption properties. Such porphyrin conjugates can afford valuable advantages in applications of TPA materials such as in photodynamic therapy and imaging of biological entities.
Central zinc metal-controlled regioselective: meso -bromination of zincated β-silylporphyrins - rapid access to meso,β-dual-functionalized porphyrins
Hayashi, Satoshi,Takamatsu, Rina,Takeda, Shiori,Noji, Masahiro,Takanami, Toshikatsu
, p. 9791 - 9795 (2020)
A convenient method for the preparation of meso,β-dual-functionalized porphyrin was developed. The bromination of zincated β-silylporphyrin with NBS selectively yielded meso-bromo-β-silylporphyrin, whereas, the bromination of free-base β-silylporphyrin selectively yielded β-bromoporphyrin via an ipso-substitution of the silyl group. These meso,β-dual-functionalized porphyrins could be used as multipurpose synthons for fabricating various porphyrin derivatives. This journal is
Porphyrin dimers and arrays
Ryan, Aoife,Gehrold, Andreas,Perusitti, Romain,Pintea, Monica,Fazekas, Marijana,Locos, Oliver B.,Blaikie, Frances,Senge, Mathias O.
experimental part, p. 5817 - 5844 (2011/11/29)
Current applications of porphyrins in medicine and optics, such as photodynamic therapy or nonlinear absorbers, increasingly require the use of far-red absorbing dyes. Modifications of the porphyrin structure to accommodate these conditions can be achieve
Synthesis and ligand binding properties of triptycene-linked porphyrin arrays
Finnigan, Eimear M.,Rein, Regis,Solladié, Nathalie,Dahms, Katja,G?tz, Daniel C.G.,Bringmann, Gerhard,Senge, Mathias O.
body text, p. 1126 - 1134 (2011/03/22)
Multiporphyrin arrays are a complex class of molecules with numerous potential applications in energy transfer, photomedicine, and light harvesting. We have developed a facile/versatile route to a class of triptycene-linked porphyrin arrays via both Suzuk
