(4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

Base Information

Chemical Name:(4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl
CAS No.:109583-44-0
Molecular Formula:C₂₆H₂₇Co₂NO₉Si
Molecular Weight:643.574
Hs Code.:

Synonyms:(4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

Suppliers and Price of (4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

There total 1 articles about (4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 102286-03-3
Co₂(CO)6((CH₃)3SiCCCHCH₃OCH₃)

: 77877-20-4
(4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one

: 109530-31-6
(4R,5S)-3-((2S,3S)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

: 109583-44-0
(4R,5S)-3-((2S,3R)-1-oxo-2,3-dimethyl-5-(trimethylsilyl)-4-pentynyl)-4-methyl-5-phenyl-2-oxazolidinone-dicobalt hexacarbonyl

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; Ar; soln. of propionimide, triflate cooled to 0 ° C, addn. of amine, soln. stirred for 15 min,boron enolate cooled to -78 ° C,Co compd. was added under Ar;soln. warmed to 0 .degree Cmixt. partitioned between pH 7 phosphate buffer,CH2Cl2;; extn. with CH2Cl2;evapn.,diastereomer ratios (12:1) determined by HPLC and (1)H NMR;flash chromy. (ethyl acetate/hexane),elem. anal. for major product;;
DOI:10.1021/ja00253a030