dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside
CAS No.:171503-77-8
Molecular Formula:C₇₄H₇₂O₁₇S
Molecular Weight:1265.44
Hs Code.:

Synonyms:dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

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Technology Process of dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

There total 8 articles about dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 105376-04-3,138661-53-7,113214-71-4
ethyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-glucopyranoside

: 197164-87-7
dicyclohexylmethyl 2,3,4-tri-O-benzoyl-1-thio-β-D-glucopyranoside

: 171503-77-8
dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In diethyl ether; dichloromethane; at 0 ℃;
DOI:10.1016/0040-4039(95)01222-4

Reference yield:

: 98-88-4
benzoyl chloride

: 171503-77-8
dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: DMAP / pyridine / 18 h / Ambient temperature

2: acetic acid; H₂O / 16 h / 60 °C

3: 41 percent / 4 Angstroem MS, NIS, TMSOTf / CH₂Cl₂; diethyl ether / 0.17 h / Ambient temperature

With dmap; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 4 Angstroem MS; In pyridine; diethyl ether; dichloromethane; water; acetic acid;
DOI:10.1021/jo971233k

Reference yield:

: Dicyclohexyl-methanethiol

: 171503-77-8
dicyclohexylmethyl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 18 percent / TMSOTf / CH₂Cl₂ / 16 h / Ambient temperature

2: NaOMe / CH₂Cl₂; methanol / 3 h

3: pyridine / 18 h / Ambient temperature

4: DMAP / pyridine / 18 h / Ambient temperature

5: acetic acid; H₂O / 16 h / 60 °C

6: 41 percent / 4 Angstroem MS, NIS, TMSOTf / CH₂Cl₂; diethyl ether / 0.17 h / Ambient temperature

With dmap; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; 4 Angstroem MS; sodium methylate; In pyridine; methanol; diethyl ether; dichloromethane; water; acetic acid;
DOI:10.1021/jo971233k