(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

Base Information

Chemical Name:(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol
CAS No.:256426-93-4
Molecular Formula:C₅₂H₆₀O₁₁
Molecular Weight:861.042
Hs Code.:

(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

Synonyms:(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

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Chemical Property of (2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

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Technology Process of (2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

There total 7 articles about (2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 256426-92-3
(3aS,4R,6S,7R,7aS)-7-Benzyloxy-4-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran

: 256426-93-4
(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

Guidance literature:: With acetic acid;
DOI:10.1021/ja992594f

Reference yield:

: 821-09-0
n-Pent-4-enyl alcohol

: 256426-93-4
(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

Guidance literature:: Multi-step reaction with 5 steps

1: 75 percent / Ag₂CO₃; I₂ / CH₂Cl₂

2: MeONa; MeOH

3: PPTS

4: 84 percent / NaH / dimethylformamide

5: 90 percent / 80 percent aq. AcOH

With methanol; iodine; sodium methylate; pyridinium p-toluenesulfonate; sodium hydride; acetic acid; silver carbonate; In dichloromethane; N,N-dimethyl-formamide; 1: Substitution / 2: Deacetylation / 3: acetalization / 4: benzylation / 5: deacetalization;
DOI:10.1021/ja992594f

Reference yield:

: 100-39-0
benzyl bromide

: 256426-93-4
(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-3,4-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / NaH / dimethylformamide

2: 90 percent / 80 percent aq. AcOH

With sodium hydride; acetic acid; In N,N-dimethyl-formamide; 1: benzylation / 2: deacetalization;
DOI:10.1021/ja992594f