1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Base Information

Chemical Name:1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine
CAS No.:619277-19-9
Molecular Formula:C₃₈H₃₆N₂O₉
Molecular Weight:664.712
Hs Code.:

Synonyms:1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Suppliers and Price of 1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

There total 9 articles about 1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 619277-03-1
1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

: 619277-19-9
1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1002/hlca.200390118

Reference yield:

: 40615-36-9
4,4'-dimethoxytrityl chloride

: 619277-19-9
1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: Multi-step reaction with 4 steps

1: collodine / CH₂Cl₂ / 12 h / 20 °C

2: 16.2 g / NaHCO₃; citric acid / H₂O

3: 75 percent / pyridine; CH₂Cl₂ / 3 h / -10 °C

4: 45 percent / Et₃N / CH₂Cl₂ / 12 h / 20 °C

With collodine; sodium hydrogencarbonate; triethylamine; citric acid; In pyridine; dichloromethane; water;
DOI:10.1002/hlca.200390118

Reference yield:

: 65-71-4,28806-14-6,691841-57-3
thymin

: 619277-19-9
1-{3'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: Multi-step reaction with 7 steps

1.1: BSA / acetonitrile / 0.75 h / 60 °C

1.2: 83 percent / TMS-Tf / acetonitrile / 4.5 h / 60 °C

2.1: 83 percent / NaOMe / methanol / 12 h / 20 °C

3.1: collidine / CH₂Cl₂ / 3 h / 20 °C

4.1: collodine / CH₂Cl₂ / 12 h / 20 °C

5.1: 16.2 g / NaHCO₃; citric acid / H₂O

6.1: 75 percent / pyridine; CH₂Cl₂ / 3 h / -10 °C

7.1: 45 percent / Et₃N / CH₂Cl₂ / 12 h / 20 °C

With 2,3,5-trimethyl-pyridine; benzenesulfonamide; collodine; sodium methylate; sodium hydrogencarbonate; triethylamine; citric acid; In pyridine; methanol; dichloromethane; water; acetonitrile;
DOI:10.1002/hlca.200390118