1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Base Information

Chemical Name:1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine
CAS No.:619277-03-1
Molecular Formula:C₃₈H₃₆N₂O₉
Molecular Weight:664.712
Hs Code.:

Synonyms:1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

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Chemical Property of 1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

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Technology Process of 1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

There total 8 articles about 1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 98-88-4
benzoyl chloride

: 619276-87-8
1-{2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thymine

: 619277-03-1
1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: In pyridine; dichloromethane; at -10 ℃; for 3h;
DOI:10.1002/hlca.200390118

Reference yield:

: 40615-36-9
4,4'-dimethoxytrityl chloride

: 619277-03-1
1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: Multi-step reaction with 3 steps

1: collodine / CH₂Cl₂ / 12 h / 20 °C

2: 16.2 g / NaHCO₃; citric acid / H₂O

3: 75 percent / pyridine; CH₂Cl₂ / 3 h / -10 °C

With collodine; sodium hydrogencarbonate; citric acid; In pyridine; dichloromethane; water;
DOI:10.1002/hlca.200390118

Reference yield:

: 65-71-4,28806-14-6,691841-57-3
thymin

: 619277-03-1
1-{4'-O-benzoyl-2'-O-[(4'',4'''-dimethoxytriphenyl)methyl]-α-L-arabinopyranosyl}thimine

Guidance literature:: Multi-step reaction with 6 steps

1.1: BSA / acetonitrile / 0.75 h / 60 °C

1.2: 83 percent / TMS-Tf / acetonitrile / 4.5 h / 60 °C

2.1: 83 percent / NaOMe / methanol / 12 h / 20 °C

3.1: collidine / CH₂Cl₂ / 3 h / 20 °C

4.1: collodine / CH₂Cl₂ / 12 h / 20 °C

5.1: 16.2 g / NaHCO₃; citric acid / H₂O

6.1: 75 percent / pyridine; CH₂Cl₂ / 3 h / -10 °C

With 2,3,5-trimethyl-pyridine; benzenesulfonamide; collodine; sodium methylate; sodium hydrogencarbonate; citric acid; In pyridine; methanol; dichloromethane; water; acetonitrile;
DOI:10.1002/hlca.200390118