(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

Base Information

Chemical Name:(eta.5-C₅Me₅)Ru((N-tBu)2CPh)
CAS No.:260548-62-7
Molecular Formula:C₂₅H₃₈N₂Ru
Molecular Weight:467.66
Hs Code.:

(eta.5-C<sub>5</sub>Me<sub>5</sub>)Ru((N-tBu)2CPh)

Synonyms:(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

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Chemical Property of (eta.5-C₅Me₅)Ru((N-tBu)2CPh)

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Technology Process of (eta.5-C₅Me₅)Ru((N-tBu)2CPh)

There total 2 articles about (eta.5-C₅Me₅)Ru((N-tBu)2CPh) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 288098-78-2
[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-allyl)]PF6

: sodium salt of dimethyl methylmalonate

: 260548-62-7
(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

: 123507-71-1
dimethyl (2-methyl-2-propenyl)propanedioate

Guidance literature:: In tetrahydrofuran; under Ar, standard Schlenk techniques; Ru complex reacted with 1 equiv. of Na(MeC(CO2Me)2) in THF at 0°C for 1 h; detd. by NMR spectroscopy;
DOI:10.1246/bcsj.74.1927

Reference yield: 72.0%

: (permethylcyclopentadienyl-methoxo-ruthenium)2

: Li(N(C(CH₃)3))2CC₆H₅

: 260548-62-7
(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

Guidance literature:: In tetrahydrofuran; Ru complex treated with Li compd. in THF at -78°C, mixt. warmed to room temp., 1 h; removal of solvent in vac., residue extd. with pentane;
DOI:10.1021/om990872d

Reference yield: 98.0%

: sodium hexaflorophosphate

: 260548-62-7
(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

: 81112-28-9
methyl 2-methylprop-2-enyl carbonate

: 288069-05-6
[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

Guidance literature:: In tetrahydrofuran; under Ar, standard Schlenk techniques; Ru complex treated with allylic carbonate in presence of NaPF6 (molar ratio 1:1:1) in THF at room temp.; stirred for 1 h; solvent removed in vac.; extd. several times with CH2Cl2; combined extracts filtered through Celite; solvent removed in vac.;
DOI:10.1246/bcsj.74.1927