[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

Base Information

Chemical Name:[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6
CAS No.:288069-05-6
Molecular Formula:C₂₉H₄₅N₂Ru*F₆P
Molecular Weight:667.724
Hs Code.:

Synonyms:

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Chemical Property of [(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

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Technology Process of [(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

There total 4 articles about [(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: sodium hexaflorophosphate

: 260548-62-7
(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

: 81112-28-9
methyl 2-methylprop-2-enyl carbonate

: 288069-05-6
[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

Guidance literature:: In tetrahydrofuran; under Ar, standard Schlenk techniques; Ru complex treated with allylic carbonate in presence of NaPF6 (molar ratio 1:1:1) in THF at room temp.; stirred for 1 h; solvent removed in vac.; extd. several times with CH2Cl2; combined extracts filtered through Celite; solvent removed in vac.;
DOI:10.1246/bcsj.74.1927

Reference yield: 55.0%

: ammonium hexafluorophosphate

: 260548-62-7
(eta.5-C₅Me₅)Ru((N-tBu)2CPh)

: 563-47-3
3-Chloro-2-methylpropene

: 288069-05-6
[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

Guidance literature:: In chloroform; pentane;
DOI:10.1039/b002927k

Reference yield: 52.0%

: ammonium hexafluorophosphate

: (η5-C5Me5)RuCl2(η3-CH2CMeCH2)

: 389608-57-5
[Ru(IV)(η3-CH2C(Me)CH2)(η5-C5Me5)(>eta.2-t-BuNC(Ph)N-t-Bu)]Cl

: 288069-05-6
[(η5-Me5C5)Ru((NC4H9)2CC6H5)(η3-CH2C(CH3)CH2)]PF6

Guidance literature:: In chloroform; under Ar, standard Schlenk techniques; mixt. of Ru complexes treated with NH4PF6 in CHCl3 at -78°C; warmed to room temp.; stirred for 1 h; solvent removed in vac.; purified by column chromy. (alumina, CH2Cl2); recrystd. from CH2Cl2-Et2O; elem. anal.;
DOI:10.1246/bcsj.74.1927