Technology Process of C31H42O3Si
There total 15 articles about C31H42O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); potassium phenolate;
In
toluene;
at 100 ℃;
for 2h;
enantioselective reaction;
DOI:10.1016/j.tetlet.2013.01.115
- Guidance literature:
-
With
tetrakis(triphenylphosphine) palladium(0); potassium phenolate;
In
toluene;
at 100 ℃;
for 4h;
DOI:10.1016/j.tetlet.2013.01.115
- Guidance literature:
-
Multi-step reaction with 10 steps
1.1: K2OsO2*2H2O; potassium hexacyanoferrate(III); 9-O-(9'-Phenanthryl)-dihydroquinine / 20 h / 0 °C
2.1: camphor-10-sulfonic acid / dichloromethane / Reflux
3.1: diisobutylaluminium hydride / toluene / 100 °C
4.1: Dess-Martin periodane / dichloromethane / 20 °C
5.1: n-butyllithium / tetrahydrofuran / -78 °C
5.2: -78 °C
6.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0 °C
7.1: toluene-4-sulfonic acid / methanol / 20 °C
8.1: Dess-Martin periodane / dichloromethane / 20 °C
9.1: methylmagnesium halide / tetrahydrofuran / 0 °C
9.2: 20 °C
10.1: tetrakis(triphenylphosphine) palladium(0); potassium phenolate / toluene / 4 h / 100 °C
With
tetrakis(triphenylphosphine) palladium(0); n-butyllithium; camphor-10-sulfonic acid; K2OsO2*2H2O; potassium phenolate; diisobutylaluminium hydride; Dess-Martin periodane; toluene-4-sulfonic acid; 9-O-(9'-Phenanthryl)-dihydroquinine; N-ethyl-N,N-diisopropylamine; potassium hexacyanoferrate(III);
In
tetrahydrofuran; methanol; dichloromethane; toluene;
1.1: |Sharpless Dihydroxylation / 4.1: |Dess-Martin Oxidation / 8.1: |Dess-Martin Oxidation / 9.2: |Dess-Martin Oxidation;
DOI:10.1016/j.tetlet.2013.01.115
