tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

Base Information

Chemical Name:tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate
CAS No.:839718-29-5
Molecular Formula:C₁₈H₂₄O₅S
Molecular Weight:352.452
Hs Code.:

Synonyms:tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

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Chemical Property of tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

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Technology Process of tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

There total 6 articles about tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 839718-28-4
tert-butyl 3-hydroxy-3-(4-{[(3-methoxy-3-oxopropyl)thio]-methyl}phenyl)propionate

: 839718-29-5
tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

Guidance literature:: With dipyridinium dichromate; potassium acetate; In dichloromethane; at 20 ℃;
DOI:10.1016/j.bmcl.2007.04.024

Reference yield:

: 946149-63-9
C₂₄H₄₀O₅SSi

: 839718-29-5
tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / TBAF / tetrahydrofuran / 1 h / 20 °C

2: 71 percent / PDC; AcOK / CH₂Cl₂ / 20 °C

With dipyridinium dichromate; tetrabutyl ammonium fluoride; potassium acetate; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.bmcl.2007.04.024

Reference yield:

: 839718-27-3
tert-butyl 3-(tert-butyldimethylsilyl)oxy-3-(4-chloromethylphenyl)propionate

: 839718-29-5
tert-butyl 3-(4-{[(3-methoxy-3-oxopropyl)thio]methyl}phenyl)-3-oxopropionate

Guidance literature:: Multi-step reaction with 3 steps

1: 25 percent / NEt₃; TBAI / CHCl₃ / 50 °C

2: 92 percent / TBAF / tetrahydrofuran / 1 h / 20 °C

3: 71 percent / PDC; AcOK / CH₂Cl₂ / 20 °C

With dipyridinium dichromate; tetrabutyl ammonium fluoride; potassium acetate; tetra-(n-butyl)ammonium iodide; triethylamine; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1016/j.bmcl.2007.04.024