{Ir(CO)(PPh3)(μ-pz)I}2; Hpz

Base Information

• Chemical Name: {Ir(CO)(PPh3)(μ-pz)I}2; Hpz
• CAS No.: 80462-14-2
• Molecular Formula: C₄₄H₃₆I₂Ir₂N₄O₂P₂
• Molecular Weight: 1352.99
• Mol file: 80462-14-2.mol

Synonyms:{Ir(CO)(PPh3)(μ-pz)I}2; Hpz

Chemical Property of {Ir(CO)(PPh3)(μ-pz)I}2; Hpz

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ir(CO)(PPh3)(μ-pz)I}2; Hpz

There total 6 articles about {Ir(CO)(PPh3)(μ-pz)I}2; Hpz which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

dicarbonylbis(triphenylphosphine)bis(μ-pyrazolyl)diiridium(I) (98420-38-3) → {Ir(CO)(PPh3)(μ-pz)I}2; Hpz (80462-14-2)

Guidance literature:

With I₂; In tetrahydrofuran; diethyl ether; under N2, soln. of I2 in Et2O was added dropwise with stirring at 25°C to soln. of equimolar amt. of Ir-complex in Et2O-THF, 0.5 h; washed with hexane, dried in vac.; elem. anal.;

Reference yield: 80.0%

{Ir2(CO)2(PPh3)2(μ-pz)2(CH2I)(I)}; Hpz → {Ir(CO)(PPh3)(μ-pz)I}2; Hpz (80462-14-2) + {Ir2(CO)2(PPh3)2(μ-pz)2(μ-CH2)(I)2}; Hpz

Guidance literature:

In benzene; reflux of (Ir2(CO)2(PPh3)2(μ-C3H3N2)2(CH2I)I) in benzene for 36 h (N2 atmosphere); elem. anal.; investigation of the mechanism by mass spectrometric analysis of isotopomers (educts isotopically modified); Kinetics;

DOI:10.1039/c39890000498

Reference yield:

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) → {Ir(CO)(PPh3)(μ-pz)I}2; Hpz (80462-14-2)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: I₂ / tetrahydrofuran; diethyl ether

With I₂; In tetrahydrofuran; diethyl ether;

upstream raw materials:

dicarbonylbis(triphenylphosphine)bis(μ-pyrazolyl)diiridium(I)

bis(triphenylphosphine)iridium(I) carbonyl chloride

{Ir2(μ-η2-pyrazolate)2(η4-1,4-cyclooctadiene)2}