3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

Base Information

Chemical Name:3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate
CAS No.:1392011-67-4
Molecular Formula:C₁₉H₂₂O₅
Molecular Weight:330.381
Hs Code.:

3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1<sup>(8)</sup>-ene-3,3-dicarboxylate

Synonyms:3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

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Chemical Property of 3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

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Technology Process of 3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

There total 2 articles about 3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1392011-66-3
1,3-dimethyl 2-(but-3-enyl)-2-(3-(4-methoxyphenyl)prop-2-yn-1-yl)malonate

: 1392011-67-4
3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

Guidance literature:: With JohnPhosAu(MeCN)SbF₆; In dichloromethane; at 80 ℃; for 15h; Inert atmosphere; Microwave irradiation;
DOI:10.1039/c2ob25419k

Reference yield:

: 1092400-70-8
2-(3-(p-methoxyphenyl)prop-2-ynyl)malonic acid dimethyl ester

: 1392011-67-4
3,3-dimethyl 8-(4-methoxyphenyl)bicyclo[4.2.0]oct-1⁽⁸⁾-ene-3,3-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 - 23 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: JohnPhosAu(MeCN)SbF₆ / dichloromethane / 15 h / 80 °C / Inert atmosphere; Microwave irradiation

With JohnPhosAu(MeCN)SbF₆; sodium hydride; In dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c2ob25419k