[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)

Base Information

• Chemical Name: [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)
• CAS No.: 97149-88-7
• Molecular Formula: C₄₄H₄₅CoNOP₃
• Molecular Weight: 755.762
• Mol file: 97149-88-7.mol

Synonyms:[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)

Chemical Property of [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃)

There total 1 articles about [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

{(N(CH2CH2P(C6H5)2)3)CoH} (53687-39-1,97135-32-5) + acetaldehyde (75-07-0,9002-91-9) → [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH3) (97149-88-7)

Guidance literature:

In tetrahydrofuran; CH3CHO added to soln. of Co complex in THF, mixt. left standing overnight at room temp.; crystals collected, washed with THF and n-pentane; elem. anal.;

DOI:10.1021/om00128a009

Reference yield: 90.0%

tetrafluoroboric acid + [tris(2-(diphenylphosphino)ethyl)amine]Co(COCH3) (97149-88-7) → [(tris(2-(diphenylphosphino)ethyl)amine)Co]BF4 (97135-43-8)

Guidance literature:

In tetrahydrofuran; diethyl ether; THF suspn. of Co complex reacted with slight excess of HBF4/Et2O at 0°C; crystals pptd. on standing;

DOI:10.1021/om00128a009

Reference yield: 90.0%

[tris(2-(diphenylphosphino)ethyl)amine]Co(COCH3) (97149-88-7) + methyl trifluoromethanesulfonate (333-27-7) → [(tris(2-(diphenylphosphino)ethyl)amine)Co]CF3SO3 (97149-89-8)

Guidance literature:

In tetrahydrofuran; THF suspn. of Co complex reacted with slight excess of CF3SO3Me at 0°C; crystals pptd. on standing;

DOI:10.1021/om00128a009

upstream raw materials:

{(N(CH₂CH₂P(C₆H₅)2)3)CoH}

acetaldehyde

Downstream raw materials:

{(N(CH₂CH₂P(C₆H₅)2)3)CoH}

[tris(2-(diphenylphosphino)ethyl)amine]Co(CH₃)

[(tris(2-(diphenylphosphino)ethyl)amine)Co]BF₄

[(tris(2-(diphenylphosphino)ethyl)amine)Co(CH₃)]BPh₄