(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

Base Information

Chemical Name:(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide
CAS No.:1393527-41-7
Molecular Formula:C₂₄H₃₃NO₃SSi
Molecular Weight:443.682
Hs Code.:

Synonyms:(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

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Chemical Property of (E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

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Technology Process of (E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

There total 3 articles about (E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1197983-12-2
(E)-ethyl 5-(2-hydroxyphenyl)pent-4-enoate

: 1393527-41-7
(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; triethylamine / dichloromethane / 3 h / 0 - 20 °C

2: diisobutylaluminium hydride / hexane / 2 h / -78 °C / Inert atmosphere

3: formic acid; sodium benzenesulfonate / water / 16 h / 20 °C

With dmap; formic acid; sodium benzenesulfonate; diisobutylaluminium hydride; triethylamine; In hexane; dichloromethane; water;
DOI:10.1021/ol3016989

Reference yield:

: 1393527-37-1
(E)-ethyl 5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-enoate

: 1393527-41-7
(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / hexane / 2 h / -78 °C / Inert atmosphere

2: formic acid; sodium benzenesulfonate / water / 16 h / 20 °C

With formic acid; sodium benzenesulfonate; diisobutylaluminium hydride; In hexane; water;
DOI:10.1021/ol3016989

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1393527-41-7
(E)-N-(5-(2-((tert-butyldimethylsilyl)oxy)phenyl)pent-4-en-1-ylidene)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: dmap; triethylamine / dichloromethane / 3 h / 0 - 20 °C

2: diisobutylaluminium hydride / hexane / 2 h / -78 °C / Inert atmosphere

3: formic acid; sodium benzenesulfonate / water / 16 h / 20 °C

With dmap; formic acid; sodium benzenesulfonate; diisobutylaluminium hydride; triethylamine; In hexane; dichloromethane; water;
DOI:10.1021/ol3016989