2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole

Base Information

• Chemical Name: 2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole
• CAS No.: 1612256-65-1
• Molecular Formula: C₂₇H₁₇BrOS₄
• Molecular Weight: 565.599
• Mol file: 1612256-65-1.mol

Synonyms:2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole

Chemical Property of 2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole

There total 1 articles about 2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

3-Bromophenol (591-20-8) + (9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracen-2-yl)methanol (475290-46-1) → 2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole (1612256-65-1)

Guidance literature:

With triphenylphosphine; diethylazodicarboxylate; at 0 - 20 ℃; for 18h; Inert atmosphere;

DOI:10.1039/c3ob42477d

Reference yield: 38.0%

2-(2-((3-bromophenoxy)methyl)-10-(1,3-dithiol-2-ylidene)anthracen-9-ylidene)-1,3-dithiole (1612256-65-1) + bis(pinacol)diborane (73183-34-3) → 2-(3-((9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracen-2-yl)methoxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (1612256-66-2)

Guidance literature:

With palladium diacetate; XPhos; In 1,4-dioxane; at 80 ℃; for 12h; Inert atmosphere;

DOI:10.1039/c3ob42477d

upstream raw materials:

3-Bromophenol

(9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracen-2-yl)methanol

Downstream raw materials:

2-(3-((9,10-di(1,3-dithiol-2-ylidene)-9,10-dihydroanthracen-2-yl)methoxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane