1,3,5-Tri-2-naphthylbenzene

Base Information

• Chemical Name: 1,3,5-Tri-2-naphthylbenzene
• CAS No.: 7059-70-3
• Molecular Formula: C36H24
• Molecular Weight: 456.5758
• DSSTox Substance ID: DTXSID80220885
• Nikkaji Number: J2.670.589D
• Wikidata: Q83098388
• Mol file: 7059-70-3.mol

Synonyms:1,3,5-Tri-2-naphthylbenzene;16322-13-7;2-(3,5-dinaphthalen-2-ylphenyl)naphthalene;1,3,5-Tri(naphthalen-2-yl)benzene;Naphthalene, 2,2',2''-(1,3,5-benzenetriyl)tris-;YSZC138;DTXSID80220885;1,3,5-tri-beta-naphthyl benzene;AKOS037645265;AS-59487;CS-0169826;F74618;2-[3,5-bis(naphthalen-2-yl)phenyl]naphthalene;Naphthalene,2,2',2''-(1,3,5-benzenetriyl)tris-;naphthalene, 2,2',2''-(1,2,5-benzenetriyl)tris-

Chemical Property of 1,3,5-Tri-2-naphthylbenzene

Chemical Property:

• Melting Point: 184.0 to 188.0 °C
• Boiling Point: 626.6±50.0 °C(Predicted)
• Flash Point: 350.9oC
• PSA: 0.00000
• Density: 1.177±0.06 g/cm3(Predicted)
• LogP: 10.14720
• Storage Temp.: Room Temperature, under inert atmosphere
• Solubility.: Chloroform (Sparingly), DMSO (Slightly)
• XLogP3: 10.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 456.187800766
• Heavy Atom Count: 36
• Complexity: 602

Purity/Quality:

97% ^*data from raw suppliers

1,3,5-Tri(1-naphthyl)benzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C(C=CC2=C1)C3=CC(=CC(=C3)C4=CC5=CC=CC=C5C=C4)C6=CC7=CC=CC=C7C=C6

Technology Process of 1,3,5-Tri-2-naphthylbenzene

There total 8 articles about 1,3,5-Tri-2-naphthylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

β-(1-naphthyl)nitroethylene (37630-26-5,4735-49-3) → 1,3,5-tris-(1'-naphthyl)benzene (7059-70-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 120 ℃; for 0.2h; Sealed tube;

DOI:10.1002/ejoc.201801290

Reference yield: 72.0%

1'-naphthacetophenone (941-98-0) → 1,3,5-tris-(1'-naphthyl)benzene (7059-70-3)

Guidance literature:

With ethylenediamine; trifluoroacetic acid; In nitromethane; for 48h; Reflux;

DOI:10.1016/j.tetlet.2012.03.008

Reference yield: 32.0%

1,3,5-trisbromobenzene (626-39-1) + 1-Naphthylboronic acid (13922-41-3) → 3,5-bis(1-naphthyl)-1-bromobenzene (173678-07-4) + 1,3,5-tris-(1'-naphthyl)benzene (7059-70-3)

Guidance literature:

With palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine; In methanol; toluene; at 75 ℃; Inert atmosphere;

DOI:10.1002/cjoc.201090162

upstream raw materials:

1'-naphthacetophenone

aniline hydrochloride

1,3,5-trisbromobenzene

1-Naphthylboronic acid