(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone

Base Information

• Chemical Name: (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone
• CAS No.: 1220350-86-6
• Molecular Formula: C₂₅H₁₄N₄O
• Molecular Weight: 386.412
• Mol file: 1220350-86-6.mol

Synonyms:(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone

Chemical Property of (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone

There total 2 articles about (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.3%

1,10-phenanthroline-5,6-dione (27318-90-7) + 4-benzoylbenzene-1,2-diamine (39070-63-8) → (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone (1220350-86-6)

Guidance literature:

With sulfated titania (TiO₂-SO_4^2-); In ethanol; at 20 ℃; for 0.5h;

DOI:10.1016/j.catcom.2010.04.021

Reference yield:

1,10-Phenanthroline (66-71-7) → (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone (1220350-86-6)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium bromide; sulfuric acid; nitric acid

2: acetic acid / ethanol / 12 h / 100 °C

With sulfuric acid; nitric acid; acetic acid; potassium bromide; In ethanol;

DOI:10.1021/acs.inorgchem.1c02154

Reference yield: 72.0%

bromotris(triphenylphosphine)copper(I) (15709-74-7) + (9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone (1220350-86-6) → C43H29BrCuN4OP

Guidance literature:

In dichloromethane; for 2h; Inert atmosphere;

DOI:10.3390/pharmaceutics13050764

upstream raw materials:

1,10-phenanthroline-5,6-dione

4-benzoylbenzene-1,2-diamine

1,10-Phenanthroline

Downstream raw materials:

[Cu((9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone)₂Cl]Cl

[Cu((9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)phenylmethanone)Cl₂]