Na{B(Ph)(m-FC₆H₄)3}

Base Information

• Chemical Name: Na{B(Ph)(m-FC₆H₄)3}
• CAS No.: 123026-30-2
• Molecular Formula: C₂₄H₁₇BF₃*Na
• Molecular Weight: 396.195
• Mol file: 123026-30-2.mol

Synonyms:Na{B(Ph)(m-FC₆H₄)3}

Chemical Property of Na{B(Ph)(m-FC₆H₄)3}

Chemical Property:

Purity/Quality:

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Technology Process of Na{B(Ph)(m-FC₆H₄)3}

There total 1 articles about Na{B(Ph)(m-FC₆H₄)3} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

3-fluorobromobenzene (1073-06-9) + dimethyl phenylboronate (13471-35-7) → Na{B(Ph)(m-FC6H4)3} (123026-30-2)

Guidance literature:

With magnesium; In diethyl ether; addn. of B(OMe)2Ph to Grignard soln. (prepared from 1-bromo-3-fluorobenzene and Mg), mixt. stirred (N2, 1 h); poured into Na2CO3 soln., org. phase evapd., extn. (EtOAc), evapd., yellow oil formed, from which was gained (after several further working steps) a white powder; washed (1. toluene, 2. pentane); elem. anal.;

DOI:10.1021/om00113a023

Reference yield: 7.0%

cis-dichlorobis(triethylphosphine)platinum(II) (13965-02-1,14177-93-6,15692-07-6) + Na{B(Ph)(m-FC6H4)3} (123026-30-2) + silver trifluoromethanesulfonate (2923-28-6) → trans-bis(triethylphosphino)phenylchloro platinum(II) + trans-{PtCl(m-FC6H4)(PEt3)2}

Guidance literature:

With lithium chloride; In methanol; react. of cis-PtCl2(PEt3)2 with 2 equiv of AgCF3SO3 in MeOH (-> cis-Pt(S)2(PEt3)2(2+), a not completely defined sovento complex with S = H2O or MeOH)); addn. of NaBPh(m-FC6H4)3 (3 h -> 2 arylated solvento complexes); addn. of LiCl; (195)Pt NMR spectrum;

DOI:10.1021/om00113a023

Reference yield:

cis-dichlorobis(trimethylphosphine)platinum(II) (19471-47-7,15630-86-1,21545-76-6) + Na{B(Ph)(m-FC6H4)3} (123026-30-2) + silver trifluoromethanesulfonate (2923-28-6) → cis-[Pt(C6H5)Cl(P(CH3)3)2]

Guidance literature:

With lithium chloride; In methanol; 1) cis-PtCl2(PMe3)2 with 2 equiv of AgCF3SO3 in MeOH; 2) addn. of NaBPh4 in MeOH; 3) ppt. dissolved in precooled CH2Cl2, warmed to 0 °C.; 4) addn. of LiCl (intermediates: not completely defined solvento complexes); (195)Pt NMR spectrum;

DOI:10.1021/om00113a023

upstream raw materials:

3-fluorobromobenzene

dimethyl phenylboronate