Acephenanthrylen-5(4H)-one

Base Information

• Chemical Name: Acephenanthrylen-5(4H)-one
• CAS No.: 42050-08-8
• Molecular Formula: C₁₆H₁₀O
• Molecular Weight: 218.255
• Hs Code.: 2914190090
• Mol file: 42050-08-8.mol

Synonyms:Acephenanthren-5-on;Acephenanthren-5-one;

Chemical Property of Acephenanthrylen-5(4H)-one

Chemical Property:

• Vapor Pressure: 6.25E-08mmHg at 25°C
• Boiling Point: 439.7°C at 760 mmHg
• Flash Point: 198.8°C
• PSA: 17.07000
• Density: 1.318g/cm³
• LogP: 3.73180

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acephenanthrylen-5(4H)-one

There total 6 articles about Acephenanthrylen-5(4H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenanthren-1-acetylchlorid (42050-07-7) → 5(4H)-Acephenanthrylenone (42050-08-8)

Guidance literature:

With aluminium trichloride; In carbon disulfide;

DOI:10.1039/P19730001160

Reference yield:

1-methylphenanthrene (832-69-9) → 5(4H)-Acephenanthrylenone (42050-08-8)

Guidance literature:

Multi-step reaction with 5 steps

1: NBS, (PhCO)2O₂

3: KOH / ethanol

4: SOCl₂, Py / diethyl ether

5: AlCl₃ / CS₂

With pyridine; potassium hydroxide; N-Bromosuccinimide; aluminium trichloride; thionyl chloride; dibenzoyl peroxide; In carbon disulfide; diethyl ether; ethanol;

DOI:10.1039/P19730001160

Reference yield:

1-(bromomethyl)phenanthrene (42050-05-5) → 5(4H)-Acephenanthrylenone (42050-08-8)

Guidance literature:

Multi-step reaction with 4 steps

2: KOH / ethanol

3: SOCl₂, Py / diethyl ether

4: AlCl₃ / CS₂

With pyridine; potassium hydroxide; aluminium trichloride; thionyl chloride; In carbon disulfide; diethyl ether; ethanol;

DOI:10.1039/P19730001160

upstream raw materials:

formaldehyd

phenanthrene

sodium cyanide

Phenanthren-1-acetylchlorid

Refernces

• 1、 Mulder, Patrick P. J.,Boere, Ben B.,Baart, Arthur,Cornelisse, Jan,Lugtenburg, Johan. "Synthesis and spectroscopy of nine isomeric methylacephenanthrylenes". . p. 22 - 32. Retrieved 2007/10/02.