dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Base Information

Chemical Name:dimethylnickel{1,2-bis(diphenylphosphino)ethane}
CAS No.:31387-22-1
Molecular Formula:C₂₈H₃₀NiP₂
Molecular Weight:487.184
Hs Code.:

Synonyms:dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Suppliers and Price of dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of dimethylnickel{1,2-bis(diphenylphosphino)ethane}

There total 3 articles about dimethylnickel{1,2-bis(diphenylphosphino)ethane} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: dimethyl(2,2'-bipyridyl)nickel(II)

: 31387-22-1
dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Guidance literature:: With C₂H₄(P(C₆H₅)2)2; In toluene; byproducts: (C5H4N)2; (inert gas); mixed at room temp., stirred for 30 min; pptd. with hexane, washed with hexane;
DOI:10.1016/S0022-328X(00)94431-0

Reference yield: 50.0%

: 14647-21-3
dibromo[1,2-bis(diphenylphosphino)ethane]nickel(II)

: 917-54-4
methyllithium

: 31387-22-1
dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Guidance literature:: In diethyl ether; prepn. from Ni((C6H5)2PC2H4P(C6H5)3)2)Br2 and CH3Li in ether at 0 °C, hydrolysis, processing at 0 - -10 °C;;
DOI:10.1039/J19710000639

Reference yield:

: 6063-59-8
dimethylethoxyaluminium

: 3264-82-2
nickel(II) acetylacetonate

: 31387-22-1
dimethylnickel{1,2-bis(diphenylphosphino)ethane}

Guidance literature:: With bis-(diphenylphosphino)-ethane; In diethyl ether; AlMe2(OEt) added to mixt. of Ni(acac)2 and diphosphine in Et2O at -50°C, stirred for 10 h at -20°C; ppt. sepd. by filtration, washed with Et2O, dried in vac.;
DOI:10.1246/bcsj.55.325