dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-)

Base Information

• Chemical Name: dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-)
• CAS No.: 260247-28-7
• Molecular Formula: C₂₇H₂₆FeO₂P*F₆P
• Molecular Weight: 614.287

Synonyms:dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-)

Chemical Property of dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-)

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Technology Process of dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-)

There total 1 articles about dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron⁽¹⁺⁾ hexafluorophosphate^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

hexafluorophosphoric acid + dicarbonyl(4-methyl-2E,4E-hexanedien-1-ol)(triphenylphosphine)iron → dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron(1+) hexafluorophosphate(1-) (260247-28-7)

Guidance literature:

In acetic anhydride; N2-atmosphere; dropwise addn. of HPF6 to Fe-complex at 0°C, stirring for 30 min; addn. to Et2O, decantation, dissoln. in MeNO2, pptn. on addn. to Et2O, collection (filtration), drying (vac.); elem. anal.;

DOI:10.1016/S0020-1693(99)00368-0

Reference yield: 95.0%

nitroacetic acid ethyl ester (626-35-7) + dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron(1+) hexafluorophosphate(1-) (260247-28-7) → dicarbonyl(ethyl 6-methyl-2-nitro-4Z,6E-octadienoate)(triphenylphosphine)iron

Guidance literature:

With n-butyllithium; In tetrahydrofuran; N2-atmosphere; treatment of nitroacetate with BuLi, addn. of Fe-complex,stirring at 0°C for 1 h, at 23°C for 18 h; water addn., extn. into Et2O, drying (MgSO4), concn., chromy. (SiO2, hexanes/AcOEt=3:1);

DOI:10.1016/S0020-1693(99)00368-0

Reference yield: 87.0%

dicarbonyl(1,2-dimethylpentadienyl)(triphenylphosphine)iron(1+) hexafluorophosphate(1-) (260247-28-7) + malonic acid dimethyl ester (108-59-8) → dicarbonyl[dimethyl(4'-methyl-2'Z,4'E-hexadienyl)propandioate](triphenylphosphine)iron

Guidance literature:

With n-butyllithium; In tetrahydrofuran; N2-atmosphere; treatment of malonate with BuLi, addn. of Fe-complex, stirring at 0°C for 1 h, at 23°C for 18 h; water addn., extn. into Et2O, drying (MgSO4), concn., chromy. (SiO2, hexanes/AcOEt=3:1);

DOI:10.1016/S0020-1693(99)00368-0

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