2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Base Information

Chemical Name:2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside
CAS No.:1384442-91-4
Molecular Formula:C₄₄H₅₁N₃O₈S
Molecular Weight:781.97
Hs Code.:

Synonyms:2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

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Chemical Property of 2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

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Technology Process of 2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

There total 3 articles about 2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: 1384442-76-5
2-methyl-5-tert-butylphenyl 2-O-acetyl-4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

: 1384442-64-1
5-tert-butyl-2-methylphenyl 4-O-benzyl-2-O-benzoyl-1-thio-α-L-rhamnopyranoside

: 1384442-91-4
2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: With acetyl chloride; In methanol; dichloromethane; at 20 ℃; for 4h;
DOI:10.1016/j.carres.2012.01.007

Reference yield:

: 1384442-64-1
5-tert-butyl-2-methylphenyl 4-O-benzyl-2-O-benzoyl-1-thio-α-L-rhamnopyranoside

: 1384442-91-4
2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -30 °C / Molecular sieve; Inert atmosphere

2: acetyl chloride / methanol; dichloromethane / 4 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; acetyl chloride; In methanol; dichloromethane;
DOI:10.1016/j.carres.2012.01.007

Reference yield:

: 1384442-63-0
2-methyl-5-tert-butylphenyl 1-thio-L-rhamnopyranoside

: 1384442-91-4
2-methyl-5-tert-butylphenyl 4-azido-3-O-benzyl-4,6-dideoxy-β-D-glucopyranosyl-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: camphor-10-sulfonic acid / acetonitrile / 12 h / 20 °C

1.2: 2 h / 0 - 20 °C

2.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 1 h / -30 °C / Molecular sieve; Inert atmosphere

3.1: acetyl chloride / methanol; dichloromethane / 4 h / 20 °C

With trimethylsilyl trifluoromethanesulfonate; camphor-10-sulfonic acid; acetyl chloride; In methanol; dichloromethane; acetonitrile;
DOI:10.1016/j.carres.2012.01.007