Technology Process of 5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-10,15,20-triphenylporphyrin
There total 2 articles about 5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-10,15,20-triphenylporphyrin which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylamine;
bis-triphenylphosphine-palladium(II) chloride;
In
1,2-dichloro-ethane;
(Ar); addn. of boron compd. and Pd complex to a soln. of porphyrin deriv. in dichloroethane, stirring at 75°C; filtration through silica, column chromy. (silica gel, hexane/CH2Cl2 1:1);
DOI:10.1021/om200137p
- Guidance literature:
-
Multi-step reaction with 2 steps
1: N-Bromosuccinimide
2: bis-triphenylphosphine-palladium(II) chloride; triethylamine / 1,2-dichloro-ethane / 90 °C / Inert atmosphere
With
bis-triphenylphosphine-palladium(II) chloride; N-Bromosuccinimide; triethylamine;
In
1,2-dichloro-ethane;
DOI:10.1016/j.tet.2010.12.025
- Guidance literature:
-
With
Cs2CO3;
tetrakis(triphenylphosphine) palladium(0);
In
tetrahydrofuran;
byproducts: 5,10,15,20-tetraphenylporphyrin; (Ar); heating a mixt. of boron compd., Cs salt, Pd complex and iron complex in THF at 77°C for 24-48 h; filtration through silica, washing with CH2Cl2, evapn. in vac., chromy. (silica gel, hexane/CH2Cl2 1:1);
DOI:10.1021/om200137p
